Cp2Ti(PMe3)2 in toluene
Kinetics; (Ar); for 7 h at 20°C; not isolated, detected by NMR;
参考文献
Sloan, Matthew E.; Staubitz, Anne; Clark, Timothy J.; Russell, Christopher A.; Lloyd-Jones, Guy C.; Manners, Ian
Journal of the American Chemical Society, 2010 , vol. 132, # 11 p. 3831 - 3841
di-tert-butyl peroxide in further solvent(s)
Kinetics; byproducts: (CH3)3COH; Irradiation (UV/VIS); flash photolysis with light pulses (50 Hz, 308 nm, ca. 10 ns duration) from XeCl excimer laser in cyclopropane-oxirane (1:2) at 221 K; detected by ESR spectroscopy;;
参考文献
Baban, Jehan A.; Goddard, Jeffrey P.; Roberts, Brian P.
Journal of Chemical Research, Synopses, 1986 , p. 30 - 31
Cp2Ti in not given
(Ar); B compd. added to Ti complex, reacted for 4 h; not isolated, detected by NMR;
参考文献
Sloan, Matthew E.; Staubitz, Anne; Clark, Timothy J.; Russell, Christopher A.; Lloyd-Jones, Guy C.; Manners, Ian
Journal of the American Chemical Society, 2010 , vol. 132, # 11 p. 3831 - 3841
Ca(N(SiMe3)2)2 in benzene-d6
under N2 or Ar; in NMR tube; C6D6 added to solid mixt. of Me2NHBH3 and Ca compd. (molar ratio 1:1 or 2:1) at ambient temp.; not isolated; monitored by (11)B NMR spectra; (Me2NBH2)3, small amt. of Me2NBH2 (ca. 2percent) and Ca compd. contg. NMe2BH3(1-) obtained;
参考文献
Hill, Michael S.; Hodgson, Marina; Liptrot, David J.; Mahon, Mary F.
Dalton Transactions, 2011 , vol. 40, # 30 p. 7783 - 7790
