2-甲基-4-三甲基硅基-1-丁烯-3-炔合成路线 （共 10 条）
反应条件
ethylmagnesium bromide in diethyl ether 9 h; Heating;
参考文献
Shapiro, E. A.; Lun'kova, G. V.; Dolgii, I. E.; Nefedov, O. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 6 p. 1047 - 1050
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , # 6 p. 1316 - 1319
反应条件
potassium hydrogensulfate
参考文献
Schichiew et al.
Doklady Akad.Azerbajdzansk.S.S.R.Chem.Abstr., 1958 , vol. 14, p. 687
Doklady Akad.Azerbajdzansk.S.S.R.Chem.Abstr., 1959 , p. 6993
反应条件
in diethyl ether byproducts: NaCl; Ar atmosphere, refluxing (41.5 h); filtn., volatiles (BEt3 and Me3SiCCC(Me)CH2) removal (ca. 70°C, 14 Torr); elem. anal.;
参考文献
Koester, Roland; Seidel, Guenter; Boese, Roland; Wrackmeyer, Bernd
Chemische Berichte, 1988 , vol. 121, p. 597 - 616
反应条件
dirhodium tetraacetate in dichloromethane T=20°C; 3 h; Yield given. Yields of byproduct given;
参考文献
Shapiro, E. A.; Kalinin, A. V.; Platonov, D. N.; Nefedov, O. M.
Russian Chemical Bulletin, 1993 , vol. 42, # 7 p. 1191 - 1195
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 7 p. 1248 - 1252
反应条件
in chloroform Ambient temperature;
参考文献
Vorob'eva, I. S.; Stadnichuk, M. D.
J. Gen. Chem. USSR (Engl. Transl.), 1984 , vol. 54, # 12 p. 2731 - 2741,2444 - 2453
反应条件
sodium hydrogensulfite 1) CHCl3, room temperature, 2) H2O-CHCl3; Multistep reaction. Title compound not separated from byproducts;
参考文献
Vorob'eva, I. S.; Stadnichuk, M. D.
J. Gen. Chem. USSR (Engl. Transl.), 1984 , vol. 54, # 12 p. 2731 - 2741,2444 - 2453
反应条件
sodium hydrogensulfite 1) CHCl3, room temperature, 2) H2O-CHCl3; Multistep reaction. Title compound not separated from byproducts;
参考文献
Vorob'eva, I. S.; Stadnichuk, M. D.
J. Gen. Chem. USSR (Engl. Transl.), 1984 , vol. 54, # 12 p. 2731 - 2741,2444 - 2453
反应条件
1: (i) BHCl2-Et2O, BCl3, (ii) /BRN= 1098229/, Me3N
2: Me3NO*2H2O
View Scheme
参考文献
Hassner,A.; Soderquist,J.A.
Journal of Organometallic Chemistry, 1977 , vol. 131, p. C1 - C4
反应条件
1: (i) BHCl2-Et2O, BCl3, (ii) /BRN= 1098229/, Me3N
2: Me3NO*2H2O / benzene / Heating
View Scheme
参考文献
Hassner,A.; Soderquist,J.A.
Journal of Organometallic Chemistry, 1977 , vol. 131, p. C1 - C4
反应条件
sodium hydrogensulfite
1) CHCl3, room temperature, 2) H2O-CHCl3; Multistep reaction. Title compound not separated from byproducts;
参考文献
Vorob'eva, I. S.; Stadnichuk, M. D.
J. Gen. Chem. USSR (Engl. Transl.), 1984 , vol. 54, # 12 p. 2731 - 2741,2444 - 2453
