10,10-二甲基-9-氧杂-10-硅杂-9,10-二氢菲合成路线 （共 6 条）
反应条件
n-butyllithium; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran; hexane; water
参考文献
DSM N.V.
Patent: US5817848 A1, 1998 ;
反应条件
diethyl ether
weiteres Edukt: Dichlor-dimethyl-silan;
参考文献
Hitchcock et al.
Journal of the Chemical Society, 1957 , p. 4537,4544
Full Text Show Details
Oita; Gilman
Journal of the American Chemical Society, 1957 , vol. 79, p. 339,340
反应条件
diethyl ether
weiteres Edukt: Dichlor-dimethyl-silan;
参考文献
Hitchcock et al.
Journal of the Chemical Society, 1957 , p. 4537,4544
Full Text Show Details
Oita; Gilman
Journal of the American Chemical Society, 1957 , vol. 79, p. 339,340
反应条件
in tetrahydrofuran
5 h; Heating;
参考文献
Kostenko, N. L.; Nesterova, S. V.; Toldov, S. V.; Skvortsov, N. K.; Reikhsfel'd, V. O.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 3 p. 716 - 717,632 - 634
反应条件
1: butyllithium / tetrahydrofuran / 3 h / Heating
2: 60 percent / tetrahydrofuran / 5 h / Heating
View Scheme
参考文献
Kostenko, N. L.; Nesterova, S. V.; Toldov, S. V.; Skvortsov, N. K.; Reikhsfel'd, V. O.
J. Gen. Chem. USSR (Engl. Transl.), 1987 , vol. 57, # 3 p. 716 - 717,632 - 634
反应条件
n-butyllithium
1.) Et2O, hexane, reflux, 72 h, 2.) Et2O, hexane, reflux, 4 h; Yield given. Multistep reaction;
参考文献
Chang, V. H. T.; Corey, J. Y.
Journal of Organometallic Chemistry, 1980 , vol. 190, # 3 p. 217 - 227
