1: 2-Fluorobenzyl alcohol With trifluoromethylsulfonic anhydride; bis-(phenyl)-sulfoxide; N,N,N',N'-tetra-methylnaphthalene-1,8-diamine in toluene T=-78°C; 2: sodium salt of dimethylmalonate in tetrahydrofuran; toluene T=-78 - 20°C;
参考文献
Takuwa, Tomofumi; Minowa, Tomofumi; Fujisawa, Hidehiko; Mukaiyama, Teruaki
Chemical and Pharmaceutical Bulletin, 2005 , vol. 53, # 5 p. 476 - 480
N,N'-bis(2-pyridylmethyl)-(1R,2R)-cyclohexane-1,2-diamine; molybdenum hexacarbonate in tetrahydrofuran
Alkylation; 0.0833333 h; microwave irradiation; Product distribution; Further Variations:SolventsTemperaturesirradiation power and reaction time;
参考文献
Kaiser, Nils Fredrik K.; Bremberg, Ulf; Larhed, Mats; Moberg, Christina; Hallberg, Anders
Angewandte Chemie - International Edition, 2000 , vol. 39, # 20 p. 3596 - 3598
[Ir(μ-Cl)(1,5-cyclooctadiene)]2; 2-lt;(4S-iPr)oxazolin-2-ylgt;Phlt;P(4-CF3C6H4)2gt; in tetrahydrofuran
24 h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
[.eta.3-C3H5PdCl2]2; (1,5-homopiperazinyl)-(Ph2P)2
0.75 h; Product distribution; Further Variations:Reagents;
参考文献
Izubiri, Mireia Rodriguez; Slawin, Alexandra M. Z.; Cole-Hamilton, David; Woollins, J. Derek
Phosphorus, Sulfur and Silicon and Related Elements, 2001 , vol. 168-169, p. 117 - 120
carbon monoxide in tetrahydrofuran
P=760.051 Torr;
参考文献
Krska, Shane W.; Hughes, David L.; Reamer, Robert A.; Mathre, David J.; Sun, Yongkui; Trost, Barry M.
Journal of the American Chemical Society, 2002 , vol. 124, # 43 p. 12656 - 12657
