1: 1-phenylallyl benzoate With C48H50IrNO4P in tetrahydrofuran
T=0°C; 3 h; Inert atmosphere;
2: sodium salt of dimethylmalonate in tetrahydrofuran
T=0°C; 14 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Stanley, Levi M.; Bai, Chen; Ueda, Mitsuhiro; Hartwig, John F.
Journal of the American Chemical Society, 2010 , vol. 132, # 26 p. 8918 - 8920
[Ir(μ-Cl)(1,5-cyclooctadiene)]2; 2-lt;(4S-iPr)oxazolin-2-ylgt;Phlt;P(4-CF3C6H4)2gt; in tetrahydrofuran
24 h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
