3 A molecular sieve; potassium carbonate; [(o-Tol)2PC6H4CH2Pd(OAc)]2 in N,N-dimethyl acetamide T=130°C; 17 h;

dihydrogen peroxide in tetrahydrofuran; water 0.533333 h;

3 A molecular sieve; potassium carbonate; [(o-Tol)2PC6H4CH2Pd(OAc)]2 in N,N-dimethyl acetamide T=130°C; 17 h;

N,N-dimethyl-formamide in N,N-dimethyl-formamide Kinetics; oxidn. of tris(p-fluorophenyl)phosphine with Mo(VI)-complex compd. in purified DMF at different temps. (UV/VIS-spectrophotometrically monitored, anaerobic conditions); rate constants detd., react. mechanism discussed;

in pentane T=-80.15°C; Kinetics; Further Variations:Solvents;

in not given Kinetics; solns. of oxo complex and phosphine are mixed in spectrophotometric cellpH 3.0; spectrophotometry;

in benzene-d6 T=38°C; Rate constant;

in acetone T=-85°C; Kinetics;