(8R,9S,10R,13S,14S)-10,13-二甲基-1,2,3,8,9,11,12,14,15,16-十氢环戊烯并[a]菲-4,7,17-三酮合成路线 （共 7 条）
→
184435-18-5(8R,9S,10R,13S,14S)-10,13-二甲基-1,2,3,8,9,11,12,14,15,16-十氢环戊烯并[a]菲-4,7,17-三酮
反应条件
chromium(VI) oxide in acetone 0.166667 h; Ambient temperature;
参考文献
Hanson, James R.; Kiran, Ismail; Masarwah, Natheer F.; Uyanik, Cavit
Journal of Chemical Research, Miniprint, 1998 , # 9 p. 2420 - 2434
→
184435-18-5(8R,9S,10R,13S,14S)-10,13-二甲基-1,2,3,8,9,11,12,14,15,16-十氢环戊烯并[a]菲-4,7,17-三酮
反应条件
1: 640 mg / aq. KOH / methanol / 2 h / Heating 2: 500 mg / 8 N Jones chromium trioxide reagent / acetone / 0.17 h / Ambient temperature View Scheme
参考文献
Hanson, James R.; Kiran, Ismail; Masarwah, Natheer F.; Uyanik, Cavit
Journal of Chemical Research, Miniprint, 1998 , # 9 p. 2420 - 2434
→
184435-18-5(8R,9S,10R,13S,14S)-10,13-二甲基-1,2,3,8,9,11,12,14,15,16-十氢环戊烯并[a]菲-4,7,17-三酮
反应条件
hydrogenchloride; acetic acid 0.5 h; Heating;
参考文献
Hanson, James R.; Kiran, Ismail; Masarwah, Natheer F.; Uyanik, Cavit
Journal of Chemical Research, Miniprint, 1998 , # 9 p. 2420 - 2434
→
184435-18-5(8R,9S,10R,13S,14S)-10,13-二甲基-1,2,3,8,9,11,12,14,15,16-十氢环戊烯并[a]菲-4,7,17-三酮
反应条件
sodium acetate; acetic acid 36 h; Heating;
参考文献
Hanson, James R.; Kiran, Ismail; Masarwah, Natheer F.; Uyanik, Cavit
Journal of Chemical Research, Miniprint, 1998 , # 9 p. 2420 - 2434
→
184435-18-5(8R,9S,10R,13S,14S)-10,13-二甲基-1,2,3,8,9,11,12,14,15,16-十氢环戊烯并[a]菲-4,7,17-三酮
反应条件
1: 320 mg / glacial acetic acid, CH3COONa / Heating 2: aq. AcOH, HCl / 0.5 h / Heating View Scheme
参考文献
Hanson, James R.; Kiran, Ismail; Masarwah, Natheer F.; Uyanik, Cavit
Journal of Chemical Research, Miniprint, 1998 , # 9 p. 2420 - 2434
→
184435-18-5(8R,9S,10R,13S,14S)-10,13-二甲基-1,2,3,8,9,11,12,14,15,16-十氢环戊烯并[a]菲-4,7,17-三酮
反应条件
1: 2 g / 2 h / Heating 2: pyridine / Ambient temperature 3: 60 mg / glacial AcOH, AcONa / 36 h / Heating View Scheme
参考文献
Hanson, James R.; Kiran, Ismail; Masarwah, Natheer F.; Uyanik, Cavit
Journal of Chemical Research, Miniprint, 1998 , # 9 p. 2420 - 2434
→
184435-18-5(8R,9S,10R,13S,14S)-10,13-二甲基-1,2,3,8,9,11,12,14,15,16-十氢环戊烯并[a]菲-4,7,17-三酮
反应条件
1: pyridine / Ambient temperature 2: 60 mg / glacial AcOH, AcONa / 36 h / Heating View Scheme
参考文献
Hanson, James R.; Kiran, Ismail; Masarwah, Natheer F.; Uyanik, Cavit
Journal of Chemical Research, Miniprint, 1998 , # 9 p. 2420 - 2434
