1,4-双(苯乙炔基)苯合成路线 （共 41 条）
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); potassium carbonate Sonogashira coupling; 17 h; Neat (no solvent);
参考文献
Green Chemistry, , vol. 11, # 11 p. 1821 - 1825
反应条件
(i) nBuLi, (ii) /BRN= 1880440/; Multistep reaction;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 869 - 874
反应条件
iodine in dimethyl sulfoxide
参考文献
Luzikova, E. V.; Bumagin, N. A.; Beletskaya, I. P.
Russian Chemical Bulletin, 1993 , vol. 42, # 3 p. 585 - 586
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 3 p. 616
反应条件
SO3-dioxane T=60°C; 1.66667 h;
参考文献
Synthesis, , # 7 p. 1001 - 1003
反应条件
palladium diacetate; N,N-dimethyl-formamide; potassium hydroxide T=145°C; 6 h; Inert atmosphere; optical yield given as percent destereoselective reaction;
参考文献
Li, Jie; Hua, Ruimao; Liu, Tao
Journal of Organic Chemistry, 2010 , vol. 75, # 9 p. 2966 - 2970
反应条件
1: periodic acid; acetic acid / 20 h / 55 °C 2: potassium hydroxide / ethanol; toluene; methanol / 1 h / 130 °C View Scheme
参考文献
Lim, Youngdon; Lee, Hyunchul; Lee, Soonho; Jang, Hohyoun; Hossain, Md. Awlad; Cho, Younggil; Kim, Taeho; Hong, Youngtaik; Kim, Whangi
Electrochimica Acta, 2014 , vol. 119, p. 16 - 23
反应条件
1: With tris-(dibenzylideneacetone)dipalladium(0); tri-cyclo-hexyl-phosphine in 1,4-dioxane
T=20°C; 0.25 h; Inert atmosphere;
2: With formic acid in 1,4-dioxane
T=80°C; Inert atmosphere; chemoselective reaction;
参考文献
Shen, Ruwei; Chen, Tieqiao; Zhao, Yalei; Qiu, Renhua; Zhou, Yongbo; Yin, Shuangfeng; Wang, Xiangbo; Goto, Midori; Han, Li-Biao
Journal of the American Chemical Society, 2011 , vol. 133, # 42 p. 17037 - 17044
反应条件
tri-ruthenium(0)dodecacarbonyl; water; N,N-dimethyl-formamide; triphenylphosphine; trifluoroacetic acid
T=145°C; 3 h; Inert atmosphere; stereoselective reaction;
参考文献
Shen, Ruwei; Chen, Tieqiao; Zhao, Yalei; Qiu, Renhua; Zhou, Yongbo; Yin, Shuangfeng; Wang, Xiangbo; Goto, Midori; Han, Li-Biao
Journal of the American Chemical Society, 2011 , vol. 133, # 42 p. 17037 - 17044
反应条件
C41H38BFeN3P2; hydrogen in tetrahydrofuran
T=20 - 90°C; P=7500.75 Torr; 70 h; Inert atmosphere; Overall yield = 90 percent;
参考文献
Srimani, Dipankar; Diskin-Posner, Yael; Ben-David, Yehoshoa; Milstein, David
Angewandte Chemie - International Edition, 2013 , vol. 52, # 52 p. 14131 - 14134
Angew. Chem., 2013 , vol. 125, # 52 p. 14381 - 14383
反应条件
iodine; dimethyl sulfoxide
T=155°C; 17 h;
参考文献
Yusybov; Filimonov
Synthesis, 1991 , # 2 p. 131 - 132
