萘-1,3,6,8-四酚合成路线 （共 18 条）
反应条件
Ba(OH)2·8H2O; potassium hydroxide; sodium hydroxide
T=275°C; 7.08333 h; Inert atmosphere;
参考文献
Snyder, Scott A.; Tang, Zhen-Yu; Gupta, Ritu
Journal of the American Chemical Society, 2009 , vol. 131, p. 5744 - 5745
反应条件
boron tribromide in dichloromethane
6 h; Ambient temperature;
参考文献
Viviani, Fabrice; Gaudry, Michel; Marquet, Andree
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 5 p. 1255 - 1259
反应条件
1: 99 percent / 60percent HClO4 / H2O; acetic acid
2: 97 percent / H2 / Pd/C (5percent) / ethyl acetate; ethanol
3: CH3ONa / methanol
View Scheme
参考文献
Ichinose, Koji; Ebizuka, Yutaka; Sankawa, Ushio
Chemical and Pharmaceutical Bulletin, 1989 , vol. 37, # 10 p. 2873 - 2875
反应条件
1: 97 percent / H2 / Pd/C (5percent) / ethyl acetate; ethanol
2: CH3ONa / methanol
View Scheme
参考文献
Ichinose, Koji; Ebizuka, Yutaka; Sankawa, Ushio
Chemical and Pharmaceutical Bulletin, 1989 , vol. 37, # 10 p. 2873 - 2875
反应条件
1: BF3-Et2O
2: NaOMe / methanol
View Scheme
参考文献
Baker,P.M.; Bycroft,B.W.
Chemical Communications (London), 1968 , p. 71 - 72
反应条件
1: 96 percent / K2CO3 / acetone
2: 98 percent / LiAlH4 / diethyl ether
3: 84 percent / NEt3 / CH2Cl2
4: 69 percent / BzNEt3Cl / CHCl3; H2O
5: 92 percent / Ba(OH)2 / dioxane; H2O
6: diethyl ether
7: 99 percent / 60percent HClO4 / H2O; acetic acid
8: 97 percent / H2 / Pd/C (5percent) / ethyl acetate; ethanol
9: CH3ONa / methanol
View Scheme
参考文献
Ichinose, Koji; Ebizuka, Yutaka; Sankawa, Ushio
Chemical and Pharmaceutical Bulletin, 1989 , vol. 37, # 10 p. 2873 - 2875
反应条件
1: 98 percent / LiAlH4 / diethyl ether
2: 84 percent / NEt3 / CH2Cl2
3: 69 percent / BzNEt3Cl / CHCl3; H2O
4: 92 percent / Ba(OH)2 / dioxane; H2O
5: diethyl ether
6: 99 percent / 60percent HClO4 / H2O; acetic acid
7: 97 percent / H2 / Pd/C (5percent) / ethyl acetate; ethanol
8: CH3ONa / methanol
View Scheme
参考文献
Ichinose, Koji; Ebizuka, Yutaka; Sankawa, Ushio
Chemical and Pharmaceutical Bulletin, 1989 , vol. 37, # 10 p. 2873 - 2875
反应条件
1: 84 percent / NEt3 / CH2Cl2
2: 69 percent / BzNEt3Cl / CHCl3; H2O
3: 92 percent / Ba(OH)2 / dioxane; H2O
4: diethyl ether
5: 99 percent / 60percent HClO4 / H2O; acetic acid
6: 97 percent / H2 / Pd/C (5percent) / ethyl acetate; ethanol
7: CH3ONa / methanol
View Scheme
参考文献
Ichinose, Koji; Ebizuka, Yutaka; Sankawa, Ushio
Chemical and Pharmaceutical Bulletin, 1989 , vol. 37, # 10 p. 2873 - 2875
反应条件
1: diethyl ether
2: 99 percent / 60percent HClO4 / H2O; acetic acid
3: 97 percent / H2 / Pd/C (5percent) / ethyl acetate; ethanol
4: CH3ONa / methanol
View Scheme
参考文献
Ichinose, Koji; Ebizuka, Yutaka; Sankawa, Ushio
Chemical and Pharmaceutical Bulletin, 1989 , vol. 37, # 10 p. 2873 - 2875
反应条件
1: 92 percent / Ba(OH)2 / dioxane; H2O
2: diethyl ether
3: 99 percent / 60percent HClO4 / H2O; acetic acid
4: 97 percent / H2 / Pd/C (5percent) / ethyl acetate; ethanol
5: CH3ONa / methanol
View Scheme
参考文献
Ichinose, Koji; Ebizuka, Yutaka; Sankawa, Ushio
Chemical and Pharmaceutical Bulletin, 1989 , vol. 37, # 10 p. 2873 - 2875
