10 palladium on activated charcoal; hydrogen; ethylenediamine in methanol T=20°C; P=760.051 Torr; 1 h;

quinoline; hydrogen in hexane; toluene T=20°C; stereoselective reaction;

1: With titanium(IV) isopropylate; n-butyllithium in tetrahydrofuran T=-78 - 50°C; 2: With water in tetrahydrofuran T=50°C; Further stages.;

quinoline; hydrogen in hexane; toluene T=20°C; stereoselective reaction;

1: With FeH(CO)(NO)(PPh3)2; phenyl silane; triethylamine in tetrahydrofuran T=60°C; 2: With tetrabutyl ammonium fluoride in tetrahydrofuran T=0°C; 2 h; Inert atmosphere; optical yield given as percent dediastereoselective reaction;