2-(二甲基苯甲硅烷)-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷合成路线 （共 71 条）
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: 1-methoxy-4-chlorobenzene in ethylene glycol dimethyl ether T=30°C; 1 h; Overall yield = 27 percentChromat.;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: 4-bromo-N,N-dimethyl-aniline in ethylene glycol dimethyl ether T=30°C; 1 h;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
反应条件
bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate; water; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl; triethylamine in 1,4-dioxane T=50°C; Inert atmosphere;
参考文献
Walter, Christian; Froehlich, Roland; Oestreich, Martin
Tetrahedron, 2009 , vol. 65, # 28 p. 5513 - 5520
反应条件
methanol; bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate; (R)-1,1'-bis(diphenylphosphino)-2,2'-binapthyl; triethylamine in 1,4-dioxane T=50°C; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Walter, Christian; Froehlich, Roland; Oestreich, Martin
Tetrahedron, 2009 , vol. 65, # 28 p. 5513 - 5520
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: 1-chloro-4-bromobenzene in ethylene glycol dimethyl ether T=30°C; 1 h;
参考文献
Journal of the American Chemical Society, , vol. 134, # 49 p. 19997 - 20000
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: bromobenzene in ethylene glycol dimethyl ether T=30°C; Reagent/catalyst;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: 1-bromo-2-methyl benzene in ethylene glycol dimethyl ether T=30°C; 1 h;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
反应条件
bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate; C17H20O; water; triethylamine in 1,4-dioxane T=50°C; 0.5 h; Inert atmosphere;
参考文献
Walter, Christian; Froehlich, Roland; Oestreich, Martin
Tetrahedron, 2009 , vol. 65, # 28 p. 5513 - 5520
反应条件
bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate; R-solphos; water; triethylamine in 1,4-dioxane T=50°C; 15 h; Inert atmosphere; enantioselective reaction;
参考文献
Tetrahedron, , vol. 65, # 28 p. 5513 - 5520
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: 1-methyl-5-bromoindole in ethylene glycol dimethyl ether T=30°C; 1 h;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
