2-(二甲基苯甲硅烷)-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷合成路线 （共 71 条）
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: para-bromotoluene in ethylene glycol dimethyl ether T=30°C; 1 h;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: 4-bromo-benzoic acid ethyl ester in ethylene glycol dimethyl ether T=30°C; 1 h;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
反应条件
in dichloromethane T=25°C; 2 h;
参考文献
Gryparis, Charis; Stratakis, Manolis
Organic Letters, 2014 , vol. 16, # 5 p. 1430 - 1433
反应条件
in dichloromethane T=25°C; 2 h;
参考文献
Organic Letters, , vol. 16, # 5 p. 1430 - 1433
反应条件
in dichloromethane T=25°C; 2 h;
参考文献
Gryparis, Charis; Stratakis, Manolis
Organic Letters, 2014 , vol. 16, # 5 p. 1430 - 1433
反应条件
1: pentane; tetrahydrofuran / 17 h / |Inert atmosphere 2: THF-d8 (tetrahydrofuran-d8) / 0.08 h View Scheme
参考文献
Kleeberg, Christian; Borner, Corinna
European Journal of Inorganic Chemistry, 2013 , # 15 p. 2799 - 2806
反应条件
[(1,3-bis(2,6-di-isopropyl-phenyl)imidazol-2-ylidene)CuSiMe2Ph] in N-dodecane byproducts: (CH3)2(C6H5)SiCO2Si(CH3)2C6H5, (Bpin)2O;
参考文献
Kleeberg, Christian; Cheung, Man Sing; Lin, Zhenyang; Marder, Todd B.
Journal of the American Chemical Society, 2011 , vol. 133, # 47 p. 19060 - 19063
反应条件
[((S)-binap)Rh(cod)]ClO4; water; (S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl; triethylamine in 1,4-dioxane T=50°C; Inert atmosphere; enantioselective reaction;
参考文献
Tetrahedron, , vol. 65, # 28 p. 5513 - 5520
反应条件
potassium methanolate in 1,4-dioxane T=100°C; 1 h; Overall yield = 82 percentSpectr.;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: 1-bromo-4-fluorobenzene in ethylene glycol dimethyl ether T=30°C; 1 h;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
