2-(二甲基苯甲硅烷)-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷合成路线 （共 71 条）
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: bromobenzene in ethylene glycol dimethyl ether T=30°C; 1 h;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
反应条件
catalyst:(C5H5)Pd(C3H5)/P(C6H5)3 in toluene reaction of 2.4 equiv. of octyne with boron compd. in toluene in presence of palladium compd. and triphenylphosphine at room temp.; gas chromy.;
参考文献
Ohmura, Toshimichi; Masuda, Kohei; Suginome, Michinori
Journal of the American Chemical Society, 2008 , vol. 130, # 5 p. 1526 - 1527
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: bromobenzene in ethylene glycol dimethyl ether T=30°C; Reagent/catalyst;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether T=30°C; 0.166667 h; Inert atmosphere; 2: 1-bromo-3-methyl-benzene in ethylene glycol dimethyl ether T=30°C; 1 h;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
反应条件
1: Me2PhSiBpin With methyllithium in tetrahydrofuran; diethyl ether T=-78°C; 2: chloro-trimethyl-silane in tetrahydrofuran; diethyl ether T=-78°C;
参考文献
Kawachi, Atsushi; Minamimoto, Takashi; Tamao, Kohei
Chemistry Letters, 2001 , # 12 p. 1216 - 1217
反应条件
[Ph2C3H3N2(C6H3(Me)Ph)(C6H3Et2)]BF4; copper(l) chloride; sodium t-butanolate in tetrahydrofuran
T=-78°C; 1 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Lee, Kang-Sang; Hoveyda, Amir H.
Journal of the American Chemical Society, 2010 , vol. 132, # 9 p. 2898 - 2900
反应条件
BF4(1-)*C41H35N2(1+); 1,8-diazabicyclo[5.4.0]undec-7-ene in tetrahydrofuran; water
T=22°C; 12 h; Inert atmosphere; optical yield given as percent ee;
参考文献
O'Brien, Jeannette M.; Hoveyda, Amir H.
Journal of the American Chemical Society, 2011 , vol. 133, # 20 p. 7712 - 7715
反应条件
BF4(1-)*C41H35N2(1+); 1,8-diazabicyclo[5.4.0]undec-7-ene in tetrahydrofuran; water
T=22°C; 12 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
O'Brien, Jeannette M.; Hoveyda, Amir H.
Journal of the American Chemical Society, 2011 , vol. 133, # 20 p. 7712 - 7715
反应条件
CuF(PPh3)3*2MeOH; tetra-n-butylammonium difluorotriphenylsilicate(IV) in toluene
T=20°C; 6 h; Inert atmosphereSchlenk techniqueSealed tube; Reagent/catalyst;
参考文献
Cirriez, Virginie; Rasson, Corentin; Riant, Olivier
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 16 p. 3137 - 3140
反应条件
1: benzoic acid With dicyclohexyl-carbodiimide in toluene
T=0°C; 1 h; Inert atmosphereSchlenk technique;
2: Me2PhSiBpin With copper monofluoride; tetra-n-butylammonium difluorotriphenylsilicate(IV) in toluene
T=20°C; Inert atmosphereSchlenk technique;
参考文献
Cirriez, Virginie; Rasson, Corentin; Riant, Olivier
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 16 p. 3137 - 3140
