2-(二甲基苯甲硅烷)-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷合成路线 （共 71 条）
反应条件
CuF(PPh3)3*2MeOH in tetrahydrofuran
T=20°C; Inert atmosphereSchlenk technique;
参考文献
Cirriez, Virginie; Rasson, Corentin; Riant, Olivier
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 16 p. 3137 - 3140
反应条件
CuF(PPh3)3*2MeOH in tetrahydrofuran
T=20°C; Inert atmosphereSchlenk technique;
参考文献
Cirriez, Virginie; Rasson, Corentin; Riant, Olivier
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 16 p. 3137 - 3140
反应条件
CuF(PPh3)3*2MeOH in tetrahydrofuran
T=20°C; Inert atmosphereSchlenk technique;
参考文献
Cirriez, Virginie; Rasson, Corentin; Riant, Olivier
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 16 p. 3137 - 3140
反应条件
CuF(PPh3)3*2MeOH in tetrahydrofuran
T=20°C; Inert atmosphereSchlenk technique;
参考文献
Cirriez, Virginie; Rasson, Corentin; Riant, Olivier
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 16 p. 3137 - 3140
反应条件
CuF(PPh3)3*2MeOH in tetrahydrofuran
T=20°C; Inert atmosphereSchlenk technique;
参考文献
Cirriez, Virginie; Rasson, Corentin; Riant, Olivier
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 16 p. 3137 - 3140
反应条件
C26H23N2O(1+)*F6P(1-); copper(l) chloride; sodium t-butanolate in tetrahydrofuran
T=-15°C; 1 h; Inert atmosphere; Reagent/catalyst;
参考文献
Takeda, Momotaro; Shintani, Ryo; Hayashi, Tamio
Journal of Organic Chemistry, 2013 , vol. 78, # 10 p. 5007 - 5017
反应条件
1: Me2PhSiBpin With potassium methanolate in ethylene glycol dimethyl ether
T=30°C; 0.166667 h; Inert atmosphere;
2: 9-bromo-anthracene in ethylene glycol dimethyl ether
T=30°C; 1 h;
参考文献
Yamamoto, Eiji; Izumi, Kiyotaka; Horita, Yuko; Ito, Hajime
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 19997 - 20000
反应条件
1,3-bis-(diphenylphosphino)propane; triethylamine; [(1,3-bis(Ph2P)propane)Rh(1,5-cyclooctadiene)]ClO4 in 1,4-dioxane; water
T=50°C; 16 h;
参考文献
Walter, Christian; Froehlich, Roland; Oestreich, Martin
Tetrahedron, 2009 , vol. 65, # 28 p. 5513 - 5520
反应条件
1: Me2PhSiBpin With copper(l) chloride; biphenyl-2-yl-di-tert-butyl-phosphane; sodium t-butanolate in tetrahydrofuran
T=0°C; 0.5 h; Inert atmosphere;
2: anhydrous 1-octyne in tetrahydrofuran; methanol
T=0°C; 24 h; Inert atmosphere; regioselective reaction;
参考文献
Wang, Peng; Yeo, Xue-Liang; Loh, Teck-Peng
Journal of the American Chemical Society, 2011 , vol. 133, # 5 p. 1254 - 1256
反应条件
1: Me2PhSiBpin With 1,1'-bis-(diphenylphosphino)ferrocene; copper(l) chloride; sodium t-butanolate in tetrahydrofuran
T=-20°C; 0.5 h; Inert atmosphere;
2: anhydrous 1-octyne in tetrahydrofuran; methanol
T=-20°C; 24 h; Inert atmosphere; regioselective reaction;
参考文献
Wang, Peng; Yeo, Xue-Liang; Loh, Teck-Peng
Journal of the American Chemical Society, 2011 , vol. 133, # 5 p. 1254 - 1256
