2-(二甲基苯甲硅烷)-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷合成路线 （共 71 条）
反应条件
potassium tert-butylate; copper(l) chloride in tetrahydrofuran
T=0°C; 2 h; Inert atmosphere; Reagent/catalyst;
参考文献
Takeda, Momotaro; Shintani, Ryo; Hayashi, Tamio
Journal of Organic Chemistry, 2013 , vol. 78, # 10 p. 5007 - 5017
反应条件
1: Me2PhSiBpin With sodium methylate; copper (I) cyanide in tetrahydrofuran
T=-78 - 20°C; Inert atmosphere;
2: trans-cinnamyl acetate in tetrahydrofuran
T=-78°C; Inert atmosphere;
参考文献
Vyas, Devendra J.; Oestreich, Martin
Angewandte Chemie - International Edition, 2010 , vol. 49, # 45 p. 8513 - 8515
反应条件
1: Me2PhSiBpin With sodium methylate; copper (I) cyanide in tetrahydrofuran
T=-78 - 20°C; Inert atmosphere;
2: (E)-3-phenyl-2-propen-1-yl benzoate in tetrahydrofuran
T=-78°C; Inert atmosphere;
参考文献
Vyas, Devendra J.; Oestreich, Martin
Angewandte Chemie - International Edition, 2010 , vol. 49, # 45 p. 8513 - 8515
反应条件
1: Me2PhSiBpin With sodium methylate; copper (I) cyanide in tetrahydrofuran
T=-78 - 20°C; Inert atmosphere;
2: (E)-cinnamic N-phenyl carbamate in tetrahydrofuran
T=-78°C; Inert atmosphere;
参考文献
Vyas, Devendra J.; Oestreich, Martin
Angewandte Chemie - International Edition, 2010 , vol. 49, # 45 p. 8513 - 8515
反应条件
1: Me2PhSiBpin With sodium methylate; copper (I) cyanide in tetrahydrofuran
T=-78 - 20°C; Inert atmosphere;
2: ethyl (E)-3-phenylprop-2-enyl carbonate in tetrahydrofuran
T=-78°C; Inert atmosphere;
参考文献
Vyas, Devendra J.; Oestreich, Martin
Angewandte Chemie - International Edition, 2010 , vol. 49, # 45 p. 8513 - 8515
反应条件
1: Me2PhSiBpin With sodium methylate; copper (I) cyanide in tetrahydrofuran
T=-78 - 20°C; Inert atmosphere;
2: diethyl (E)-3-phenyl-2-propen-1-yl phosphate in tetrahydrofuran
T=-78°C; Inert atmosphere;
参考文献
Vyas, Devendra J.; Oestreich, Martin
Angewandte Chemie - International Edition, 2010 , vol. 49, # 45 p. 8513 - 8515
反应条件
1: Me2PhSiBpin With sodium methylate; copper (I) cyanide in tetrahydrofuran
T=-78 - 20°C; Inert atmosphere;
2: 1-[(E)-3-bromo-1-propenyl]benzene in tetrahydrofuran
T=-78°C; Inert atmosphere;
参考文献
Vyas, Devendra J.; Oestreich, Martin
Angewandte Chemie - International Edition, 2010 , vol. 49, # 45 p. 8513 - 8515
反应条件
C31H31N2(1+)*BF4(1-); sodium methylate; copper(l) chloride in dichloromethane
T=0°C; Inert atmosphereSchlenk technique; Reagent/catalyst; Overall yield = 81 percent; enantioselective reaction;
参考文献
Delvos, Lukas B.; Vyas, Devendra J.; Oestreich, Martin
Angewandte Chemie - International Edition, 2013 , vol. 52, # 17 p. 4650 - 4653
Angew. Chem., 2013 , vol. 125, # 17 p. 4748 - 4751,4
反应条件
C26H23N2O(1+)*F6P(1-); sodium ethanolate; copper(l) chloride in tetrahydrofuran
T=0°C; 2 h; Inert atmosphere; Reagent/catalyst; Overall yield = 85 percentSpectr.; enantioselective reaction;
参考文献
Takeda, Momotaro; Shintani, Ryo; Hayashi, Tamio
Journal of Organic Chemistry, 2013 , vol. 78, # 10 p. 5007 - 5017
反应条件
toluene-4-sulfonic acid; cesium fluoride in N,N-dimethyl-formamide
T=20°C; 3 h; Inert atmosphere;
参考文献
Mita, Tsuyoshi; Chen, Jianyang; Sugawara, Masumi; Sato, Yoshihiro
Organic Letters, 2012 , vol. 14, # 24 p. 6202 - 6205
