2-(二甲基苯甲硅烷)-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷合成路线 (共 71 条)
反应条件
1: Me2PhSiBpin With copper(l) chloride; biphenyl-2-yl-di-tert-butyl-phosphane; sodium t-butanolate in tetrahydrofuran
T=0°C; 0.5 h; Inert atmosphere;
2: phenylacetylene in tetrahydrofuran; methanol
T=0°C; 24 h; Inert atmosphere; regioselective reaction;
参考文献
Wang, Peng; Yeo, Xue-Liang; Loh, Teck-Peng
Journal of the American Chemical Society, 2011 , vol. 133, # 5 p. 1254 - 1256