1: diethylzinc With methylmagnesium bromide in tetrahydrofuran T=20°C; 2: (RS,E)-N-benzylidene-2-methylpropane-2-sulfinamide in tetrahydrofuran T=-78°C; 1 h; 3: With hydrogenchloride in methanol Further stages. Title compound not separated from byproducts.;
参考文献
Almansa, Raquel; Guijarro, David; Yus, Miguel
Tetrahedron Asymmetry, 2008 , vol. 19, # 5 p. 603 - 606
1: n-pentyl-magnesium bromide With dimethyl zinc in tetrahydrofuran; toluene T=20°C; 2: (RS,E)-N-benzylidene-2-methylpropane-2-sulfinamide in tetrahydrofuran; toluene T=-78°C; 1 h; 3: With hydrogenchloride in methanol Further stages. Title compound not separated from byproducts.;
参考文献
Almansa, Raquel; Guijarro, David; Yus, Miguel
Tetrahedron Asymmetry, 2008 , vol. 19, # 5 p. 603 - 606
1: diethylzinc With methylmagnesium bromide in tetrahydrofuran T=20°C; 2: (RS,E)-N-benzylidene-2-methylpropane-2-sulfinamide in tetrahydrofuran T=-78°C; 1 h; 3: With hydrogenchloride in methanol Further stages. Title compound not separated from byproducts.;
参考文献
Almansa, Raquel; Guijarro, David; Yus, Miguel
Tetrahedron Asymmetry, 2008 , vol. 19, # 5 p. 603 - 606
1: diethylzinc With methylmagnesium bromide in tetrahydrofuran T=20°C; 2: (RS,E)-N-benzylidene-2-methylpropane-2-sulfinamide in tetrahydrofuran T=-78°C; 1 h; 3: With hydrogenchloride in methanol Further stages. Title compound not separated from byproducts.;
参考文献
Almansa, Raquel; Guijarro, David; Yus, Miguel
Tetrahedron Asymmetry, 2008 , vol. 19, # 5 p. 603 - 606
1: in diethyl ether; dichloromethane T=-48°C; Grignard reaction; 2: With hydrogenchloride in 1,4-dioxane; methanol T=20°C; Substitution; 0.5 h; Solvolysis; Title compound not separated from byproducts;
参考文献
Cogan, Derek A.; Liu, Guangcheng; Ellman, Jonathan
Tetrahedron, 1999 , vol. 55, # 29 p. 8883 - 8904
1: in diethyl ether; dichloromethane
T=-48°C; Grignard reaction;
2: With hydrogenchloride in 1,4-dioxane; methanol
T=20°C; Substitution; 0.5 h; Solvolysis; Title compound not separated from byproducts;
参考文献
Cogan, Derek A.; Liu, Guangcheng; Ellman, Jonathan
Tetrahedron, 1999 , vol. 55, # 29 p. 8883 - 8904
