1: dichlorobis(methyldiphenylsilyl)methane With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 0.0833333 h;
2: Bromure de phenyl magnesium in tetrahydrofuran; hexane
T=0°C; 1 h;
3: With pyridine; air in tetrahydrofuran; hexane
T=0°C; 1 h;
1: dichlorobis(methyldiphenylsilyl)methane With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 0.0833333 h;
2: Bromure de phenyl magnesium in tetrahydrofuran; hexane
T=0°C; 1 h;
3: With air; ammonium chloride in tetrahydrofuran; hexane; water
T=20°C; 0.5 h;
参考文献
Inoue; Kondo; Shinokubo; Oshima
Journal of the American Chemical Society, 2001 , vol. 123, # 44 p. 11109 - 11110
1.1: n-butyllithium / tetrahydrofuran; hexane / 2 h / -80 °C
1.2: 0.5 h / -80 - 0 °C
2.1: N-bromosuccinmide; water / acetone / 0.5 h / 20 °C / |Cooling with ice
View Scheme
