2,3,5-trimethyl-pyridine; 6-(2-C10H7-CH2)-1-(py-4-yl)octahydrocyclopenta[b]pyrrol-6-ol; 2-methylpropanoic anhydride in dichloromethane T=20°C; 5 h; Title compound not separated from byproducts.;
1: benzyl 4-chlorobenzoyloxycarbamate With osmium(VIII) oxide; (DHQ)2-PHAL in acetonitrile T=20°C; 0.166667 h; 2: cyclohexene in water; acetonitrile T=20°C; 3 h; optical yield given as percent eeenantioselective reaction;
参考文献
Harris, Lawrence; Mee, Simon P. H.; Furneaux, Richard H.; Gainsford, Graeme J.; Luxenburger, Andreas
Journal of Organic Chemistry, 2011 , vol. 76, # 2 p. 358 - 372
(DHQD)2PHAL; potassium dioxotetrahydroxoosmate(VI); water in propan-1-ol 2 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Li, Guigen; Angert, Hubert H.; Sharpless, K. Barry
Angewandte Chemie, 1996 , vol. 108, # 23/24 p. 2995 - 2999