1: RuBnCl2(PCy3)2 / benzene / 4 h / 20 °C 2: 99 percent / HF*pyridine / tetrahydrofuran / 2 h / 25 °C 3: 49 percent / 3,3-dimethyldioxirane / CH2Cl2; acetone / 2 h / -50 - -30 °C View Scheme
参考文献
Schinzer, Dieter; Limberg, Anja; Bauer, Armin; Boehm, Oliver M.; Cordes, Martin
Angewandte Chemie (International Edition in English), 1997 , vol. 36, # 5 p. 523 - 524
1: [o-(OiPr)C6H4CH=RuCl2PCy3] / CH2Cl2 / 5 h / 20 °C
2: HF; pyridine / tetrahydrofuran / 20 °C
View Scheme
参考文献
MASSACHUSETTS INSTITUTE OF TECHNOLOGY; TRUSTEES OF BOSTON COLLEGE; HOVEYDA, Amir H.; YU, Miao; WANG, Chenbo; SCHROCK, Richard R.
Patent: WO2012/167171 A2, 2012 ;
1: C52H67Cl2NOW / benzene; toluene / 2.5 h / 22 °C / 1 Torr / |Inert atmosphere; |Glovebox
2: pyridine hydrogenfluoride / tetrahydrofuran / 36 h / 22 °C / |Inert atmosphere
View Scheme
参考文献
Wang, Chenbo; Yu, Miao; Kyle, Andrew F.; Jakubec, Pavol; Dixon, Darren J.; Schrock, Richard R.; Hoveyda, Amir H.
Chemistry - A European Journal, 2013 , vol. 19, # 8 p. 2726 - 2740
