188290-36-0合成路线 （共 917 条）
反应条件
1: thiophene With n-butyllithium in tetrahydrofuran T=-75°C; 1 h; Inert atmosphere; 2: With zinc(II) chloride−TMEDA in tetrahydrofuran T=-75 - 20°C; 3: 1-bromo-4-methoxy-benzene Further stages;
参考文献
Seggio, Anne; Jutand, Anny; Priem, Ghislaine; Mongin, Florence
Synlett, 2008 , # 19 p. 2955 - 2960
反应条件
potassium tetrachloropalladate in ethanol; water 24 h; Ambient temperature;
参考文献
Wang, Dong-Liang; Hwang, Wen-Shu
Journal of Organometallic Chemistry, 1991 , vol. 406, # 3 p. C29 - C32
反应条件
copper diacetate; mercury(II) diacetate; lithium bromide; palladium dichloride P=37503 Torr; 20 h; Ambient temperature;
参考文献
Jaouhari, R.; Dixneuf, P. H.; Lecolier, S.
Tetrahedron Letters, 1986 , vol. 27, # 52 p. 6315 - 6318
反应条件
copper diacetate; mercury(II) trifluoroacetate; lithium bromide; palladium dichloride P=37503 Torr; 20 h; Ambient temperature;
参考文献
Jaouhari, R.; Dixneuf, P. H.; Lecolier, S.
Tetrahedron Letters, 1986 , vol. 27, # 52 p. 6315 - 6318
反应条件
copper diacetate; mercury(II) trifluoroacetate; lithium bromide; palladium dichloride P=37503 Torr; 20 h; Ambient temperatureeffect of further mercury salts, further alkali salts, addition of HBF4, increasing the reaction temperature or presence of copper(II) salts; (one-pot carbonylation of other heterocyclic compounds, use of other alcohols); Product distributionMechanism;
参考文献
Jaouhari, R.; Dixneuf, P. H.; Lecolier, S.
Tetrahedron Letters, 1986 , vol. 27, # 52 p. 6315 - 6318
反应条件
in ethanol; water byproducts: tetrathiophene; at room temp. for 24 h under N2; concn.; extn. (CHCl3); combined CHCl3-extracts were concd.; chromy. (n-hexane; silica gel); NMR;
参考文献
Wang, Dong-Liang; Hwang, Wen-Shu
Journal of Organometallic Chemistry, 1991 , vol. 406, # 3 p. C29 - C32
反应条件
aluminium trichloride; glycolonitrile
参考文献
Steinkopf; Ohse
Justus Liebigs Annalen der Chemie, 1924 , vol. 437, p. 19
反应条件
in thiophene was heated at 70°C for 2h; was filtered; filtrate was concentrated under reduced pressure; was diluted with hexane; GLC;
参考文献
Fuchita, Yoshio; Hiraki, Katsuma; Kamogawa, Yasuko; Suenaga, Miho; Tohgoh, Kazutaka; Fujiwara, Yuzo
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 4 p. 1081 - 1085
参考文献
Wynberg; Bantjes
Journal of Organic Chemistry, 1959 , vol. 24, p. 1421
反应条件
T=876.84 - 926.84°C; IR laser powering; Product distribution; Further Variations:Reagents;
参考文献
Hore, Nathan R.; Russell, Douglas K.
New Journal of Chemistry, 2004 , vol. 28, # 5 p. 606 - 613
