188290-36-0合成路线 （共 917 条）
参考文献
Ford; Mackay
Journal of the Chemical Society, 1957 , p. 4620,4622
反应条件
di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium; 4,4'-di-tert-butyl-2,2'-dipyridyl in octane T=80°C; 16 h;
参考文献
Takagi, Jun; Sato, Kazuaki; Hartwig, John F; Ishiyama, Tatsuo; Miyaura, Norio
Tetrahedron Letters, 2002 , vol. 43, # 32 p. 5649 - 5651
反应条件
1: thiophene With n-butyllithium; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran; hexane 0.5 h; Heating; 2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran; hexane T=-78 - -20°C; 19 h;
参考文献
Usta, Hakan; Lu, Gang; Facchetti, Antonio; Marks, Tobin J.
Journal of the American Chemical Society, 2006 , vol. 128, # 28 p. 9034 - 9035
反应条件
(iPrPNP)CoCH2SiMe3 in neat (no solvent) T=60°C; 24 h; Inert atmosphereGlovebox;
参考文献
Obligacion, Jennifer V.; Semproni, Scott P.; Chirik, Paul J.
Journal of the American Chemical Society, 2014 , vol. 136, # 11 p. 4133 - 4136
反应条件
di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium; 4,4'-di-tert-butyl-2,2'-dipyridyl in octane T=80°C; 16 h;
参考文献
Takagi, Jun; Sato, Kazuaki; Hartwig, John F; Ishiyama, Tatsuo; Miyaura, Norio
Tetrahedron Letters, 2002 , vol. 43, # 32 p. 5649 - 5651
反应条件
hydrogen bromide; acetic acid T=5 - 20°C;
参考文献
Jorgensen, Mikkel; Krebs, Frederik C.
Journal of Organic Chemistry, 2005 , vol. 70, # 15 p. 6004 - 6017
反应条件
1.) glow discharge, 2.) -196 deg C -> -80 deg C; Further byproducts given. Title compound not separated from byproducts;
参考文献
Skramstad, Jan; Chaudhry, Mohammed Shoaib; Garvang, Arne
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1984 , vol. 38, # 6 p. 509 - 512
反应条件
1: thiophene With n-butyllithium; magnesium bromide in tetrahydrofuran T=20°C; 2 h; 2: 1-bromo-4-methoxy-benzene With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in tetrahydrofuran 18 h; Heating;
参考文献
Bayh, Omar; Awad, Hacan; Mongin, Florence; Hoarau, Christophe; Trecourt, Francois; Queguiner, Guy; Marsais, Francis; Blanco, Fernando; Abarca, Belen; Ballesteros, Rafael
Tetrahedron, 2005 , vol. 61, # 20 p. 4779 - 4784
反应条件
silver fluoride; PdCl2(PPh2(CH2)4PPh2) in dimethyl sulfoxide T=60°C; 5 h;
参考文献
Masui, Kentaro; Mori, Atsunori; Okano, Kunihiko; Takamura, Kenji; Kinoshita, Motoi; Ikeda, Tomiki
Organic Letters, 2004 , vol. 6, # 12 p. 2011 - 2014
反应条件
1: thiophene With 2,2,6,6-tetramethyl-piperidine; n-butyllithium; cobalt(II) dibromide in tetrahydrofuran; hexane T=0 - 20°C; 0.5 h; 2: para-iodoanisole in tetrahydrofuran; hexane T=20°C; 2 h; 3: With water in tetrahydrofuran; hexane
参考文献
Dayaker, Gandrath; Chevallier, Floris; Gros, Philippe C.; Mongin, Florence
Tetrahedron, 2010 , vol. 66, # 46 p. 8904 - 8910
