(R)-2-(4-(苄氧基)-3-硝基苯基)环氧乙烷合成路线 （共 6 条）
反应条件
sodium hydroxide in methanol 0.5 h;
参考文献
Hett, Robert; Fang, Qun Kevin; Gao, Yun; Hong, Yaping; Butler, Hal T.; Nie, Xiaoyi; Wald, Stephen A.
Tetrahedron Letters, 1997 , vol. 38, # 7 p. 1125 - 1128
反应条件
1: 87 percent / BH3*THF / tetrahydrofuran / -20 °C 2: lipase PS Celite-immobilized / various solvent(s) / 72 h / 37 °C 3: K2CO3 / methanol / 2.5 h / 20 °C View Scheme
参考文献
Hett, Robert; Fang, Qun Kevin; Gao, Yun; Hong, Yaping; Butler, Hal T.; Nie, Xiaoyi; Wald, Stephen A.
Tetrahedron Letters, 1997 , vol. 38, # 7 p. 1125 - 1128
反应条件
potassium carbonate in methanol T=20°C; Cyclization; 2.5 h; Title compound not separated from byproducts;
参考文献
Campos, Francisco; Bosch, M. Pilar; Guerrero, Angel
Tetrahedron Asymmetry, 2000 , vol. 11, # 13 p. 2705 - 2717
反应条件
potassium carbonate in methanol T=20°C; Cyclization; 2.5 h; Title compound not separated from byproducts;
参考文献
Campos, Francisco; Bosch, M. Pilar; Guerrero, Angel
Tetrahedron Asymmetry, 2000 , vol. 11, # 13 p. 2705 - 2717
反应条件
1: 82 percent / Br2 / CHCl3 / 25 °C 2: 87 percent / BH3*THF / tetrahydrofuran / -20 °C 3: lipase PS Celite-immobilized / various solvent(s) / 72 h / 37 °C 4: K2CO3 / methanol / 2.5 h / 20 °C View Scheme
参考文献
Campos, Francisco; Bosch, M. Pilar; Guerrero, Angel
Tetrahedron Asymmetry, 2000 , vol. 11, # 13 p. 2705 - 2717
反应条件
1: lipase PS Celite-immobilized / various solvent(s) / 72 h / 37 °C 2: K2CO3 / methanol / 2.5 h / 20 °C View Scheme
参考文献
Campos, Francisco; Bosch, M. Pilar; Guerrero, Angel
Tetrahedron Asymmetry, 2000 , vol. 11, # 13 p. 2705 - 2717
