2-(三氟甲基)-2-丙烯酸 2-甲基三环[3.3.1.1(3,7)]癸-2-基酯合成路线 （共 5 条）
反应条件
lithium carbonate; triethylamine; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran T=100°C; P=7500.75 Torr; 15 h; Product distribution / selectivity;
参考文献
Tosoh F-Tech, Inc.; SAGAMI CHEMICAL RESEARCH CENTER
Patent: EP1637514 A1, 2006 ;
Location in patent: Page/Page column 19 ;
反应条件
lithium carbonate; triethylamine; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran T=100°C; P=7500.75 Torr; 15 h; Product distribution / selectivity;
参考文献
Tosoh F-Tech, Inc.; SAGAMI CHEMICAL RESEARCH CENTER
Patent: EP1637514 A1, 2006 ;
Location in patent: Page/Page column 22; 23 ;
反应条件
sodium hydroxide; sulfuric acid in toluene
参考文献
TOSOH CORPORATION
Patent: US2003/139613 A1, 2003 ;
反应条件
triethylamine in tetrahydrofuran
参考文献
TOSOH CORPORATION
Patent: US2003/139613 A1, 2003 ;
反应条件
1: adamantane monoketone (adamantanone); (α-trifluoromethyl)acryloyl chloride With methylmagnesium bromide in tetrahydrofuran T=20°C; 2 h; Heating / reflux; 2: (α-trifluoromethyl)acryloyl chloride T=20°C; 2 h; Heating / reflux;
参考文献
Daicel Chemical Industries, Ltd.
Patent: JP2005/112824 A, 2005 ;
Location in patent: Page/Page column 12-13 ;
