9,9-二己基-2,7-二溴代芴合成路线 （共 22 条）
反应条件
1: 2,7-dibromo-9H-fluorene With tetra-(n-butyl)ammonium iodide; sodium hydroxide in water 0.75 h; Inert atmosphere; 2: 1-bromo-hexane in water T=70°C; 1 h; Inert atmosphere;
参考文献
Saikia, Gunin; Iyer, Parameswar K.
Journal of Organic Chemistry, 2010 , vol. 75, # 8 p. 2714 - 2717
反应条件
bromine; iron(III) chloride in chloroform T=0 - 20°C; 3 h;
参考文献
Destri, Silvia; Pasini, Mariacecilia; Botta, Chiara; Porzio, William; Bertini, Fabio; Marchio, Luciano
Journal of Materials Chemistry, 2002 , vol. 12, # 4 p. 924 - 933
反应条件
1: 80 percent / aq. H2SO4; acetic acid; Br2 / KBrO3 / 4 h / 40 - 55 °C 2: 91 percent / t-BuOK / tetrahydrofuran / 4 h / 20 °C View Scheme
参考文献
Chemical Communications, , # 27 p. 3397 - 3399
反应条件
sodium hydroxide; Aliquatreg; 336 in water; toluene T=55 - 75°C; 33.5 h;
参考文献
Adaway, Timothy J.; Gonzalez, Michael A.; Wu, Weishi
Patent: US2004/122266 A1, 2004 ;
Location in patent: Page 2-3 ;
反应条件
1: NaOH; water; [C6H5N(CH3)3]Cl / dimethylsulfoxide / 24 h / 60 °C 2: Br; I; NaHSO3 / CH2Cl2 / 20 h / 20 °C View Scheme
参考文献
Chemistry Letters, , vol. 33, # 10 art. no. CL-040604, p. 1290 - 1291
反应条件
1: 99 percent / PdCl2; Et3N; PPh3 / 5 h / 150 °C 2: 89 percent / DIBAL / tetrahydrofuran / 3 h / -78 °C 3: 97 percent / PBr3 / benzene / 6 h / 45 °C View Scheme
参考文献
Jin, Youngeup; Ju, Jeongmin; Kim, Jinwoo; Lee, Sungeun; Kim, Jin Young; Park, Sung Heum; Son, Se-Mo; Jin, Sung-Ho; Lee, Kwanghee; Suh, Hongsuk
Macromolecules, 2003 , vol. 36, # 19 p. 6970 - 6975
反应条件
1.1: n-BuLi / tetrahydrofuran / 1 h / -78 °C 1.2: 51 percent / tetrahydrofuran / 18 h / 20 °C 2.1: 93 percent / NaBH4 / ethanol / 6 h / 20 °C 3.1: 85 percent / SOCl2 / benzene / 4 h / 50 °C 4.1: 90 percent / dimethylformamide / 5 h / 100 °C 5.1: 86 percent / NaOH / H2O / 18 h / 20 °C View Scheme
参考文献
Wang, Weiling; Xu, Jianwei; Lai, Yee-Hing; Wang, Fuke
Macromolecules, 2004 , vol. 37, # 10 p. 3546 - 3553
反应条件
bis-triphenylphosphine-palladium(II) chloride; 2,6-di-tert-butyl-phenol in toluene Stille coupling;
参考文献
Mikroyannidis, John A.; Cheung, Kai Yin; Fung, Man Kin; Djurisic, Aleksandra B.
Reactive and Functional Polymers, 2010 , vol. 70, # 7 p. 426 - 432
反应条件
1.1: Mg / tetrahydrofuran 1.2: tetrahydrofuran / -78 - 20 °C 2.1: toluene / Heating View Scheme
参考文献
Ling; Kang; Neoh; Huang, Wei
Macromolecules, 2003 , vol. 36, # 19 p. 6995 - 7003
