palladium-gold in neat (no solvent, gas phase)
Kinetics; NO redn. by CO and (18)O2 over AuPd(100) catalyst was studied; polarisation-modulation IR reflection absorption, QMS, LEED, Auger spectroscopy;
参考文献
Gao, Feng; Wang, Yilin; Goodman, D. Wayne
Journal of Catalysis, 2009 , vol. 268, # 1 p. 115 - 121
in neat (no solvent)
introducing CO2 into glass container with H2(18)O, keeping for at least a day at room temp.; release of CO2 isotopomer by slowly warming CO2/H2O mixture from liquid nitrogen temp.;
参考文献
Xu, Yunjie; Jaeger, Wolfgang
Journal of Molecular Structure, 2001 , vol. 599, p. 211 - 217
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反应条件
in gas
Kinetics; flowing afterglow technique at 298 K in He;
参考文献
O'Hair, Richard A.J.; Sheldon, John C.; Bowie, John H.; Damrauer, Robert; DePuy, Charles H.
Australian Journal of Chemistry, 1989 , vol. 42, # 4 p. 489 - 496
Baulch, D. L.; Breckenridge, W. H.
Transactions of the Faraday Society, 1966 , vol. 62, p. 2768 - 2773
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Gmelin Handbook: C: MVol.C2, 3.5, page 192 - 192
Preston, K. F.; Cvetanovich, R. J.
Journal of Chemical Physics, 1966 , vol. 45, p. 2888 - 2893
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Gmelin Handbook: C: MVol.C2, 3.7.5.2, page 200 - 200
in further solvent(s)
heated for 16 h at 80°C / statistical mixt. of labelled CO2 produced; monitored by MS;
参考文献
Choudhury, Dibakar; Cole-Hamilton, David J.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1982 , p. 1885 - 1894
in neat (no solvent, gas phase)
methane oxidn. with (18)O2 in presence of LaMnO(3+x) under static conditions; working gas mixt.: Ar, CH4 and (18)O2; total initial pressure 150 Pa; heated above 735 K; monitored by mass spectrometry;
参考文献
Mazo; Kudryashov; Kemnitz
Russian Journal of Physical Chemistry A, 2001 , vol. 75, # 7 p. 1113 - 1119
(Ni(2'-hydroxy-4',5'-dimethylacetophenone-4-methylthiosemicarbazone))2
Kinetics; oxidn. of CO with methylviologene in presence of H2(18)O and of Ni complex as catalyst;
参考文献
Lu, Zheng; White, Corbet; Rheingold, Arnold L.; Crabtree, Robert H.
Angewandte Chemie, 1993 , vol. 105, # 1 p. 121 - 123
