(R)-1-氯-2-丙醇合成路线 (共 10 条)
反应条件
oxygen; lithium chloride; copper dichloride; [Pd2(MeCOCHCOCHCOMe){(S)-Ph-BINAP}X2] in tetrahydrofuran; water T=25°C; Oxidation; P=760 Torr; Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 63, # 9 p. 2790 - 2791
反应条件
Cu(L-Asp)(1,2-bis(4-pyridyl)ethylene)0.5(H2O)0.5(MeOH)0.5 T=25°C;
参考文献
Chemical Communications, , # 11 p. 1287 - 1289
反应条件
hydrogenchloride; (R,R)-[Co(salen)]*GaCl3 in diethyl ether T=0 - 4°C; 1 h;
参考文献
Journal of Organometallic Chemistry, , vol. 691, # 9 p. 1862 - 1872
反应条件
hydrogenchloride in carbon disulfide
参考文献
Tetrahedron, , vol. 25, p. 1807 - 1816
反应条件
1: 1-chloro-propan-2-ol With Candida antarctica lipase B in isopropyl alcohol T=30°C; 0.5 h; Enzymatic reaction; 2: vinyl acetate in isopropyl alcohol T=30°C; 0.0833333 h; Enzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Tetrahedron, , vol. 65, # 46 p. 9583 - 9591
反应条件
1: 1-chloro-propan-2-ol With Burkholderia cepacia lipase in isopropyl alcohol T=30°C; 0.5 h; Enzymatic reaction; 2: vinyl acetate in isopropyl alcohol T=30°C; 0.266667 h; Enzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Tetrahedron, , vol. 65, # 46 p. 9583 - 9591
反应条件
copper dichloride; [Pd(CH3CN)2{(S)-BINAP}](BF4)2; heptane-2,4,6-trione in tetrahydrofuran T=25°C; Product distribution; Further Variations:CatalystsSolventsReagents;
参考文献
Journal of Organometallic Chemistry, , vol. 603, # 1 p. 50 - 60
反应条件
glycerol dehydrogenase; 2-propanol-NAD(1+) potassium phosphate buffer, pH 7;
参考文献
Tetrahedron Letters, , vol. 29, # 20 p. 2453 - 2454
参考文献
Tetrahedron Asymmetry, , vol. 8, # 3 p. 359 - 362
反应条件
phosphate buffer; Pseudomonas lipase Amano AH; (2R-trans)-2-(3,4-dihydroxyphenyl)-3,4-dihydro-2H-1-benzopyran-3,5,7-triol T=30°C; pH=7.0; 48 h; Product distribution; Further Variations:Reagents;
参考文献
Tetrahedron Asymmetry, , vol. 13, # 4 p. 415 - 422