9-(4-甲基苯基)-9H-咔唑合成路线 （共 25 条）
反应条件
1: potassium tert-butylate; [2,2']bipyridinyl; copper(l) iodide / toluene / 24 h / 100 °C / |Inert atmosphere; |Sealed tube 2: Cu(I)[(CH3CN)4]BF4; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; 2,9-dimethyl-1,10-phenanthroline; iodine; methyloxirane / tetrahydrofuran / 20 h / 20 °C / |Flow reactor; |Inert atmosphere; |Irradiation View Scheme
参考文献
Hernandez-Perez, Augusto C.; Collins, Shawn K.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 48 p. 12696 - 12700
Angew. Chem., 2013 , vol. 125, # 48 p. 12928 - 12932
反应条件
Cu(I)[(CH3CN)4]BF4; 2,9-dimethyl-1,10-phenanthroline; iodine; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; methyloxirane in tetrahydrofuran T=20°C; 20 h; Flow reactorInert atmosphereIrradiation; Catalytic behavior; Overall yield = 70 percent; Overall yield = 34 mg;
参考文献
Hernandez-Perez, Augusto C.; Collins, Shawn K.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 48 p. 12696 - 12700
Angew. Chem., 2013 , vol. 125, # 48 p. 12928 - 12932
反应条件
N-bromosuccinmide in N,N-dimethyl-formamide T=20°C; 3 h;
参考文献
Wong, Wai-Yeung; Liu, Li; Cui, Dongmui; Leung, Louis M.; Kwong, Chin-Fai; Lee, Tik-Ho; Ng, Ho-Fung
Macromolecules, 2005 , vol. 38, # 12 p. 4970 - 4976
反应条件
N-bromosuccinmide in dichloromethane
参考文献
Yu, Fang-Fang; Fan, He-Liang; Huang, Hai-Fang; Cao, Qian-Yong; Dai, Yan-Feng; Gao, Xi-Cun; Shang, Yu-Zhu; Zhang, Min-Yan; Long, Li; Xu, Hong; Li, Xi-Feng; Wei, Bin
Inorganica Chimica Acta, 2012 , vol. 390, p. 119 - 122
反应条件
KIO3; acetic acid; potassium iodide
T=100°C; 1 h;
参考文献
Solvay SA
Patent: EP2433928 A1, 2012 ;
Location in patent: Page/Page column 10 ;
