lithium hydroxide in tetrahydrofuran

1: H2 / Pd/C 2: aq. LiOH / tetrahydrofuran View Scheme

1: 89 percent / tBuOK 2: H2 / Pd/C 3: aq. LiOH / tetrahydrofuran View Scheme

1: LiAlH4 / tetrahydrofuran / 72 h / Heating 2: celite; 4 Angstroem molecular sieves; pyridinium chlorochromate / CH2Cl2 3: toluene / 4 h / Heating 4: H2 / 20percent Pd(OH)2/C / methanol / 20 h / 760.05 Torr 5: LiOH*H2O / H2O; tetrahydrofuran / 20 h / 20 °C View Scheme

1: celite; 4 Angstroem molecular sieves; pyridinium chlorochromate / CH2Cl2 2: toluene / 4 h / Heating 3: H2 / 20percent Pd(OH)2/C / methanol / 20 h / 760.05 Torr 4: LiOH*H2O / H2O; tetrahydrofuran / 20 h / 20 °C View Scheme

[Rh(OH)(cycloocta-1,5-diene)]2; water T=100°C; Miyaura-Hayashi reaction; 16 h; Inert atmosphere;