James, B. D.; Wallbridge, M. G. H.
Progress Inorg. Chem., 1970 , vol. 11, p. 99 - 231
Full Text Show Details
Gmelin Handbook: B: B-Verb.8, 1.2, page 2 - 5
in neat (no solvent) addn. of diborane to amine at liquid N2 temp., keeping at -111°C, -78°C and 0°C consecutively, stirring at 0°C for 4-6 h (vacuum line); cooling to -78°C, removal of B2H6 by distn.;
catalyst:dimethyl ether byproducts: ester of methyl boric acid; from 0°C (28 d) to 24°C (2 d); maximum yield at 22°C (5 d)and at molar ratio of (CF3)2PH:B2H6=1.875:2.577; very pure products;
in diethyl ether addn. of diborane to amine soln. at liquid N2 temp., keeping at -111°C, -78°C and 0°C consecutively, stirring at 0°C for 4-6 h (vacuum line); cooling to -78°C, removal of B2H6 by distn.;
参考文献
Gatti; Wartik
Inorganic Chemistry, 1966 , vol. 5, p. 2075
in diethyl ether pyrolysis in diphenylether at 215 °C;;
参考文献
Tebbe, F. N.; Garratt, P. M.; Hawthorne, M. F.
Journal of the American Chemical Society, 1968 , vol. 90, p. 869 - 879
Full Text View citing articles Show Details
Gmelin Handbook: B: B-Verb.2, 6.1, page 190 - 191
