byproducts: isobutan, boron hydride; High Pressure; under N2; diborane and trihalogen-borane was added to t-butylbenzene at-130°C, then in a closed autoclave the mixture was heated to 130°C for 40 min; at -195.8°C H2 was removed, at room temp. the residue of trihalogen-borane and diborane were removed, unseparable isomers; elem. anal.;
in neat (no solvent)
addn. of diborane to amine at liquid N2 temp., keeping at -111°C, -78°C and 0°C consecutively, stirring at 0°C for 4-6 h (vacuum line); cooling to -78°C, removal of B2H6 by distn.;
参考文献
Brown, Herbert C.; Murray, Leo T.
Inorganic Chemistry, 1984 , vol. 23, p. 2746 - 2753
decompn. by heating in presence of catalytic amount of diborane;
参考文献
Vahrenkamp, H.
Journal of Organometallic Chemistry, 1971 , vol. 28, p. 181 - 192
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Gmelin Handbook: B: B-Verb.3, 2.7.1, page 21 - 24
Mikhailov, B. M.; Akhnazarian, A. A.; Vasiliev, L. S.
Doklady Akademii Nauk SSSR, 1961 , vol. 136, p. 828 - 831
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Gmelin Handbook: B: B-Verb.14, 5.6, page 212 - 224
