anthracene; triethylamine in benzene 1 h; Irradiation;

1: in 1,4-dioxane Irradiation; 2: T=100°C;

1: 54 percent / lead tetraacetate, acetic acid / CH2Cl2 / 0 °C 2: 1.) O3, 2.) triphenylphosphine / 1.) CH2Cl2, -78 deg C, 2.) CH2Cl2, -78 deg C, 30 min 3: 1.) phenyllithium / 1.) THF, 2.) benzene, THF, 3 min 4: 85 percent / aq. acetic acid / tetrahydrofuran / 15 h 5: H2, NaHCO3; / 5percent Pt/C / benzene; ethanol / 24 h 6: NaOH / benzene; methanol / 0.33 h / Ambient temperature 7: 1.) hydrazine, 2.) dianisyl telluroxide / 1.) ethanol, reflux, overnight, 2.) water, CH2Cl2, 1,2-dibromotetrachloroethane, 5 h 8: 82 percent / triethylamine, anthracene / benzene / 1 h / Irradiation View Scheme

1: 1.) phenyllithium / 1.) THF, 2.) benzene, THF, 3 min 2: 85 percent / aq. acetic acid / tetrahydrofuran / 15 h 3: H2, NaHCO3; / 5percent Pt/C / benzene; ethanol / 24 h 4: NaOH / benzene; methanol / 0.33 h / Ambient temperature 5: 1.) hydrazine, 2.) dianisyl telluroxide / 1.) ethanol, reflux, overnight, 2.) water, CH2Cl2, 1,2-dibromotetrachloroethane, 5 h 6: 82 percent / triethylamine, anthracene / benzene / 1 h / Irradiation View Scheme

1: 85 percent / aq. acetic acid / tetrahydrofuran / 15 h 2: H2, NaHCO3; / 5percent Pt/C / benzene; ethanol / 24 h 3: NaOH / benzene; methanol / 0.33 h / Ambient temperature 4: 1.) hydrazine, 2.) dianisyl telluroxide / 1.) ethanol, reflux, overnight, 2.) water, CH2Cl2, 1,2-dibromotetrachloroethane, 5 h 5: 82 percent / triethylamine, anthracene / benzene / 1 h / Irradiation View Scheme

1: 1.) phenyllithium / 1.) THF, 2.) benzene, THF, 3 min 2: 85 percent / aq. acetic acid / tetrahydrofuran / 15 h 3: H2, NaHCO3; / 5percent Pt/C / benzene; ethanol / 24 h 4: NaOH / benzene; methanol / 0.33 h / Ambient temperature 5: 1.) hydrazine, 2.) dianisyl telluroxide / 1.) ethanol, reflux, overnight, 2.) water, CH2Cl2, 1,2-dibromotetrachloroethane, 5 h 6: 82 percent / triethylamine, anthracene / benzene / 1 h / Irradiation View Scheme

1: 1.) O3, 2.) triphenylphosphine / 1.) CH2Cl2, -78 deg C, 2.) CH2Cl2, -78 deg C, 30 min 2: 1.) phenyllithium / 1.) THF, 2.) benzene, THF, 3 min 3: 85 percent / aq. acetic acid / tetrahydrofuran / 15 h 4: H2, NaHCO3; / 5percent Pt/C / benzene; ethanol / 24 h 5: NaOH / benzene; methanol / 0.33 h / Ambient temperature 6: 1.) hydrazine, 2.) dianisyl telluroxide / 1.) ethanol, reflux, overnight, 2.) water, CH2Cl2, 1,2-dibromotetrachloroethane, 5 h 7: 82 percent / triethylamine, anthracene / benzene / 1 h / Irradiation View Scheme

1: H2, NaHCO3; / 5percent Pt/C / benzene; ethanol / 24 h 2: NaOH / benzene; methanol / 0.33 h / Ambient temperature 3: 1.) hydrazine, 2.) dianisyl telluroxide / 1.) ethanol, reflux, overnight, 2.) water, CH2Cl2, 1,2-dibromotetrachloroethane, 5 h 4: 82 percent / triethylamine, anthracene / benzene / 1 h / Irradiation View Scheme

1: in tetrahydrofuran; diethyl ether T=-78 - -40°C; 12 h; Darknesssolid phase reaction; 2: With methanol in tetrahydrofuran; diethyl ether T=-78°C;

Pseudonocardia autotrophica 100U-19 cells in ethanol T=30°C; 72 h;