N-(2,2-二甲基丙酰基)-3-(三氟甲基)苯胺合成路线 （共 7 条）
参考文献
The Trustees of Princeton University
Patent: US5248781 A1, 1993 ;
反应条件
copper(l) chloride in tert-butyl alcohol T=30°C; 24 h; Inert atmosphereSealed tube; Catalytic behavior; SolventTemperatureTime; regioselective reaction;
参考文献
Cai, Shangjun; Chen, Chao; Sun, Zelin; Xi, Chanjuan
Chemical Communications, 2013 , vol. 49, # 40 p. 4552 - 4554
反应条件
1: triethylamine / ethyl acetate / 40 °C / |Inert atmosphere; |Sealed tube 2: copper(l) chloride / tert-butyl alcohol / 24 h / 30 °C / |Inert atmosphere; |Sealed tube View Scheme
参考文献
Cai, Shangjun; Chen, Chao; Sun, Zelin; Xi, Chanjuan
Chemical Communications, 2013 , vol. 49, # 40 p. 4552 - 4554
反应条件
1: triethylamine / ethyl acetate / 40 °C / |Inert atmosphere; |Sealed tube 2: copper(l) chloride / tert-butyl alcohol / 24 h / 30 °C / |Inert atmosphere; |Sealed tube View Scheme
参考文献
Cai, Shangjun; Chen, Chao; Sun, Zelin; Xi, Chanjuan
Chemical Communications, 2013 , vol. 49, # 40 p. 4552 - 4554
反应条件
1: 1.) BuLi / 1.) ether, hexane, 4 h, 2.) ether, hexane, overnight 2: 78.3 percent / KOH / ethane-1,2-diol / 8 h / 160 °C View Scheme
参考文献
Heterocycles, , vol. 38, # 10 p. 2243 - 2246
反应条件
1: 1.) BuLi / 1.) ether, hexane, 4 h, 2.) ether, hexane, overnight 2: 78.3 percent / KOH / ethane-1,2-diol / 8 h / 160 °C 3: 86 percent / ethane-1,2-diol / 6 h / 160 °C 4: 90 percent / KOH / methanol / 3 h / Heating View Scheme
参考文献
Jaouhari, Rabih; Quinn, Philip
Heterocycles, 1994 , vol. 38, # 10 p. 2243 - 2246
反应条件
n-butyllithium 1.) ether, hexane, 4 h, 2.) ether, hexane, overnight; Yield given. Multistep reaction;
参考文献
The Trustees of Princeton University
Patent: US5248781 A1, 1993 ;
