双环[2.2.1]庚烷-2-甲醛合成路线 (共 10 条)
反应条件
4-acetylamino-2,2,6,6-tetramethylpiperidine-N-oxyl; toluene-4-sulfonic acid in dichloromethane 1) 0 deg C, 1 h, 2) r.t., 2 h;
参考文献
Ma, Zhenkun; Bobbitt, James M.
Journal of Organic Chemistry, 1991 , vol. 56, # 21 p. 6110 - 6114
反应条件
oxoammonium resin in dichloromethane T=20°C; 1 h; Title compound not separated from byproducts;
参考文献
Weik, Steffen; Nicholson, Graeme; Jung, Gnther; Rademann, Jrg
Angewandte Chemie - International Edition, 2001 , vol. 40, # 8 p. 1436 - 1439
反应条件
cobalt(II) dibromide; zinc in toluene; tert-butyl alcohol T=25 - 110°C; 16 h;
参考文献
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, , vol. 40, # 10 p. 989 - 993
参考文献
Bulletin de la Societe Chimique de France, , p. 2472 - 2478
反应条件
2: HCO2H View Scheme
参考文献
Bulletin de la Societe Chimique de France, , p. 2472 - 2478
反应条件
W(CO)3Cl2(AsPh3)2 in benzene T=80°C; 1 h; water instead of alcohol, labeling with D2O; Product distributionMechanism;
参考文献
Journal of Organometallic Chemistry, , vol. 294, p. C5 - C8
反应条件
(i) nBuLi, THF, (ii) aq. H2O2; Multistep reaction;
参考文献
Chemistry Letters, , p. 961 - 962
反应条件
Fe2(CO)9 in anhydrous butyl ether 48 h; Heating;
参考文献
Bankston, Donald
Journal of Organic Chemistry, 1989 , vol. 54, # 8 p. 2003 - 2006
反应条件
Fe2(CO)9 in tetrahydrofuran 48 h; Heating;
参考文献
Bankston, Donald
Journal of Organic Chemistry, 1989 , vol. 54, # 8 p. 2003 - 2006
反应条件
(i), (ii) H2, Pt, (iii) aq. HCl; Multistep reaction;
参考文献
Boissier,J.R. et al.
Chimica Therapeutica, 1966 , vol. 1, p. 320 - 326