1-硝基-4-苯基乙炔苯合成路线 （共 107 条）
反应条件
1,3-dimethyl-imidazolidin-2-one; potassium carbonate; triphenylphosphine; copper(l) chloride
T=120°C; 12 h;
参考文献
Ogawa, Daisuke; Li, Jing; Suetsugu, Masato; Jiao, Jiao; Iwasaki, Masayuki; Nishihara, Yasushi
Tetrahedron Letters, 2013 , vol. 54, # 6 p. 518 - 521
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium acetate in butan-1-ol
T=80°C; 48 h;
参考文献
Catellani, Marta; Chiusoli, Gian Paolo; Mari, Aristodemo
Journal of Organometallic Chemistry, 1984 , vol. 275, # 1 p. 129 - 138
反应条件
carbon monoxide; bis(η3-allyl-μ-chloropalladium(II)) in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 0.5 h;
参考文献
Bumagin, N. A.; Bumagina, I. G.; Kashin, A. N.; Beletskaya, I. P.
Doklady Chemistry, 1981 , vol. 261, p. 532 - 535
Dokl. Akad. Nauk SSSR Ser. Khim., 1981 , vol. 261, # 5 p. 1141 - 1144
反应条件
aluminum oxide; potassium fluoride; triphenylphosphine; copper(l) iodide; palladium
Substitution; Sonogashira reaction; 0.0416667 h; Irradiationin 1000 W microwave oven;
参考文献
Kabalka, George W.; Wang, Lei; Namboodiri, Vasudevan; Pagni, Richard M.
Tetrahedron Letters, 2000 , vol. 41, # 27 p. 5151 - 5154
反应条件
palladium diacetate; triphenylphosphine in N,N-dimethyl acetamide
T=80°C; P=760 Torr; 1 h;
参考文献
Kakusawa, Naoki; Kurita, Jyoji
Chemical and Pharmaceutical Bulletin, 2006 , vol. 54, # 5 p. 699 - 702
反应条件
1: iodobenzene; 2-methyl-but-3-yn-2-ol With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine
T=50°C; 1 h; Inert atmosphere;
2: para-nitro iodo-benzene With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; potassium hydroxide
T=110°C; 5 h; Inert atmosphere;
参考文献
Zhao, Yankai; Liu, Qiang; Li, Jing; Liu, Zhongquan; Zhou, Bo
Synlett, 2010 , # 12 p. 1870 - 1872
反应条件
N,N-dimethyl acetamide; PdCl2(pyCH2SMe); tetrabutyl-ammonium chloride; sodium carbonate
T=25°C; Sonogashira coupling; 24 h; Inert atmosphere;
参考文献
Jones, Roderick C.; Canty, Allan J.; Caradoc-Davies, Tom; Davies, Noel W.; Gardiner, Michael G.; Marriott, Philip J.; Ruehle, Christian P. G.; Tolhurst, Vicki-Anne
Dalton Transactions, 2010 , vol. 39, # 16 p. 3799 - 3801
反应条件
tetrakis(triphenylphosphine) palladium(0); copper(I) thiophene-2-carboxylate; triethylamine in 1,4-dioxane
T=110°C; 24 h; Inert atmosphereSealed tubeSchlenk technique; chemoselective reaction;
参考文献
Quan, Zheng-Jun; Lv, Ying; Jing, Fu-Qiang; Jia, Xiao-Dong; Huo, Cong-De; Wang, Xi-Cun
Advanced Synthesis and Catalysis, 2014 , vol. 356, # 2-3 p. 325 - 332
反应条件
(Ph3P)2Pd(Ph)(I) in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 10 h;
参考文献
Bumagin, N. A.; Bumagina, I. G.; Beletskaya, I. P.
Doklady Chemistry, 1983 , vol. 272, p. 333 - 336
Dokl. Akad. Nauk SSSR Ser. Khim., 1983 , vol. 272, # 6 p. 1384 - 1388
反应条件
acetic acid; sodium nitrite in tetrahydrofuran
1 h; Ambient temperature;
参考文献
Beccalli, Egle M.; Manfredi, Amedea; Marchesini, Alessandro
Journal of Organic Chemistry, 1985 , vol. 50, # 13 p. 2372 - 2375
