1H,1H,2H-全氟-1-己烯合成路线 （共 26 条）
反应条件
HOF* CH3CN in dichloromethane 3 h; 0 deg C to RT;
参考文献
Hung, Ming H.; Smart, Bruce E.; Feiring, Andrew E.; Rozen, Shlomo
Journal of Organic Chemistry, 1991 , vol. 56, # 9 p. 3187 - 3189
反应条件
1: With benzo[1,3,2]dioxaborole; [Rh[(R)-BINAP](COD)]BF4 in tetrahydrofuran T=0°C; 1 h; 2: With sodium hydroxide; dihydrogen peroxide in ethanol Further stages. Title compound not separated from byproducts.;
参考文献
Segarra, Anna M.; Claver, Carmen; Fernandez, Elena
Chemical Communications, 2004 , # 4 p. 464 - 465
反应条件
1: With Wilkinson's catalyst in tetrahydrofuran T=20°C; 2.5 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran Further stages. Title compound not separated from byproducts.;
参考文献
Ramachandran, P. Veeraraghavan; Jennings, Michael P.; Brown, Herbert C.
Organic Letters, 1999 , vol. 1, # 9 p. 1399 - 1402
反应条件
1: With Wilkinson's catalyst in tetrahydrofuran T=20°C; 1 h; 2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran Further stages. Title compound not separated from byproducts.;
参考文献
Ramachandran, P. Veeraraghavan; Jennings, Michael P.; Brown, Herbert C.
Organic Letters, 1999 , vol. 1, # 9 p. 1399 - 1402
反应条件
1: With bis(cyclohexanyl)borane in tetrahydrofuran T=20°C; 16 h; 2: With dihydrogen peroxide in tetrahydrofuran alkaline solution; Further stages.;
参考文献
Ramachandran, P. Veeraraghavan; Jennings, Michael P.
Chemical Communications, 2002 , # 4 p. 386 - 387
反应条件
1: 88 percent / H2PtCl6*6H2O / propan-2-ol / 110 °C 2: 83 percent / LiAlH4 / diethyl ether / 2 h / Heating View Scheme
参考文献
Benouargha; Boulahia; Boutevin; Caporiccio; Guida-Pietrasanta; Ratsimihety
Phosphorus, Sulfur and Silicon and Related Elements, 1996 , vol. 113, # 1-4 p. 79 - 87
反应条件
hydroxide
T=-40.15 - 98.85°C; Oxidation; P=10 - 300 Torr; Kinetics; Further Variations:Reagents;
参考文献
Vesine; Bossoutrot; Mellouki; Le Bras; Wenger; Sidebottom
Journal of Physical Chemistry A, 2000 , vol. 104, # 37 p. 8512 - 8520
反应条件
1: With Wilkinson's catalyst in tetrahydrofuran
T=20°C; 2.5 h;
2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran
Further stages. Title compound not separated from byproducts.;
参考文献
Ramachandran, P. Veeraraghavan; Jennings, Michael P.; Brown, Herbert C.
Organic Letters, 1999 , vol. 1, # 9 p. 1399 - 1402
反应条件
1: With Wilkinson's catalyst in tetrahydrofuran
T=20°C; 1 h;
2: With sodium hydroxide; dihydrogen peroxide in tetrahydrofuran
Further stages. Title compound not separated from byproducts.;
参考文献
Ramachandran, P. Veeraraghavan; Jennings, Michael P.; Brown, Herbert C.
Organic Letters, 1999 , vol. 1, # 9 p. 1399 - 1402
反应条件
1: [Rh(COD)(dppb)](1+)*BF4(1-) / tetrahydrofuran / 0.75 h / -25 °C
2: H2O2; NaOH
View Scheme
参考文献
Brown, Herbert C.; Chen, Guang-Ming; Jennings, Michael P.; Ramachandran, P. Veeraraghavan
Angewandte Chemie - International Edition, 1999 , vol. 38, # 13-14 p. 2052 - 2054
