alpha,2,6-三甲基苄醇合成路线 （共 12 条）
反应条件
potassium hydrogensulfate; hydroquinone T=180°C; P=120 Torr;
参考文献
Knorr, Rudolf; Behringer, Claudia; Noeth, Heinrich; Schmidt, Martin; Lattke, Ernst; Raepple, Edith
Chemische Berichte, 1997 , vol. 130, # 5 p. 585 - 592
反应条件
1: activated Al2O3 / 270 - 280 °C / 10 Torr 2: KMnO4; aqueous KOH / Erwaermen des Reaktionsprodukts mit H2SO4, Aethanol und Benzol View Scheme
参考文献
Schwartzman; Corson
Journal of the American Chemical Society, 1954 , vol. 76, p. 781,783
反应条件
potassium dichromate; sulfuric acid
参考文献
Schwartzman; Corson
Journal of the American Chemical Society, 1954 , vol. 76, p. 781,783
反应条件
1: 1-bromo-2,6-dimethyl-benzene With iodine; magnesium in tetrahydrofuran
T=40°C; 0.333333 h;
2: acetaldehyde in tetrahydrofuran
1 h; Heating; Further stages.;
参考文献
Noji, Masahiro; Konno, Yosuke; Ishii, Keitaro
Journal of Organic Chemistry, 2007 , vol. 72, # 14 p. 5161 - 5167
反应条件
lithium aluminium tetrahydride
参考文献
Reuvers,A.J.M. et al.
Tetrahedron, 1969 , vol. 25, p. 4455 - 4465
反应条件
1: Mg; I2 / tetrahydrofuran / 0.5 h / Heating
2: tetrahydrofuran
View Scheme
参考文献
Spivey, Alan C.; Fekner, Tomasz; Spey, Sharon E.
Journal of Organic Chemistry, 2000 , vol. 65, # 10 p. 3154 - 3159
反应条件
diethyl ether; lithium
anschliessend Behandeln mit Acetaldehyd;
参考文献
Schwartzman; Corson
Journal of the American Chemical Society, 1954 , vol. 76, p. 781,783
参考文献
Kamikawa,T. et al.
Tetrahedron, 1968 , vol. 24, p. 2091 - 2100
反应条件
1: (i) (diazotization), (ii) aq. HBr, Cu
2: (i) Mg, BrCH2CH2Br, (ii) CdCl2, (iii) /BRN= 605303/
3: LiAlH4
View Scheme
参考文献
Reuvers,A.J.M. et al.
Tetrahedron, 1969 , vol. 25, p. 4455 - 4465
参考文献
Kamikawa,T. et al.
Tetrahedron, 1968 , vol. 24, p. 2091 - 2100
