4,6-二甲基-2-庚酮合成路线 （共 19 条）
反应条件
water; hydrogen; zirconium phosphate/palladium T=90 - 110°C; P=1035.1 - 4140.41 Torr; Neat (no solvent); Product distribution / selectivity;
参考文献
UNION CARBIDE CHEMICALS and PLASTICS TECHNOLOGY CORPORATION; DOW GLOBAL TECHNOLOGIES INC.
Patent: WO2007/38440 A1, 2007 ;
Location in patent: Page/Page column 8-9; 1/3; 2/3 ;
反应条件
water; hydrogen; zirconium oxide/copper/chromium P=0 - 1807.68 Torr; Neat (no solvent); Product distribution / selectivity;
参考文献
UNION CARBIDE CHEMICALS and PLASTICS TECHNOLOGY CORPORATION; DOW GLOBAL TECHNOLOGIES INC.
Patent: WO2007/38440 A1, 2007 ;
Location in patent: Page/Page column 10; 3/3 ;
反应条件
1: H2 / Pd-C / ethanol 2: diethyl ether View Scheme
参考文献
Hinnen,A.; Dreux,J.
Bulletin de la Societe Chimique de France, 1964 , p. 1492 - 1498
反应条件
1: NaOAc, AcOH / benzene 2: H2 / Pd-C / ethanol 3: diethyl ether View Scheme
参考文献
Hinnen,A.; Dreux,J.
Bulletin de la Societe Chimique de France, 1964 , p. 1492 - 1498
反应条件
diethyl ether anschliessend mit wss.Ammoniumchlorid-Loesunge;
参考文献
Hinnen,A.; Dreux,J.
Bulletin de la Societe Chimique de France, 1964 , p. 1492 - 1498
参考文献
Guerbet
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909 , vol. 149, p. 131
Chem. Zentralbl., 1909 , vol. 80, # II p. 1537
反应条件
P=735.5 Torr; Ambient temperature(catalytic hydrogenation);
参考文献
Hinnen,A.; Dreux,J.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1962 , vol. 255, p. 1747 - 1749
反应条件
P=735.5 Torr; Ambient temperature(catalytic hydrogenation);
参考文献
Hinnen,A.; Dreux,J.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1962 , vol. 255, p. 1747 - 1749
反应条件
lithium aluminium tetrahydride; aluminum tri-bromide 1.) benzene, 30 - 40 deg C, 10 min, 2.) dichloroethane, -20 deg C, 1 h; 25 deg C, 0.5 h; Yield given. Multistep reaction;
参考文献
Gorobets, E. V.; Shitikova, O. V.; Lomakina, S. I.; Tolstikov, G. A.; Kuchin, A. V.
Russian Chemical Bulletin, 1993 , vol. 42, # 9 p. 1573 - 1578
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 9 p. 1637 - 1642
反应条件
anschliessend mit wasserhaltiger Phosphorsaeure;
参考文献
Lorz,W.
Diss.<Karlsruhe 1956>S.21
