2,2-二甲基-5-己烯-3-醇合成路线 （共 22 条）
反应条件
manganese; zinc(II) chloride in ethyl acetate
T=50°C;
参考文献
Cahiez; Chavant
Tetrahedron Letters, 1989 , vol. 30, # 52 p. 7373 - 7376
反应条件
1: With iron(III) chloride in nitromethane
T=20°C; 1 h;
2: With hydrogenchloride
T=20°C; 0.5 h;
参考文献
Watahiki, Tsutomu; Oriyama, Takeshi
Tetrahedron Letters, 2002 , vol. 43, # 49 p. 8959 - 8962
反应条件
hydrogenchloride in tetrahydrofuran
T=20°C; 5 h;
参考文献
Yanagisawa, Akira; Inoue, Hirokuni; Morodome, Miwa; Yamamoto, Hisashi
Journal of the American Chemical Society, 1993 , vol. 115, # 22 p. 10356 - 10357
反应条件
ruthenium trichloride; carbon monoxide; triethylamine in 1,4-dioxane; water
T=80°C; P=1551.49 Torr; 24 h;
参考文献
Denmark, Scott E.; Nguyen, Son T.
Organic Letters, 2009 , vol. 11, # 3 p. 781 - 784
反应条件
tetra-(n-butyl)ammonium iodide in dichloromethane; water
T=20°C; 0.25 h;
参考文献
Thadani, Avinash N.; Batey, Robert A.
Organic Letters, 2002 , vol. 4, # 22 p. 3827 - 3830
反应条件
1: diethyl allyl phosphate With Bu5CrLi2 in tetrahydrofuran
T=-78°C; 0.0833333 h;
2: pivalaldehyde in tetrahydrofuran
T=-78°C; 0.5 h; Further stages.;
参考文献
Hojo; Sakuragi; Okabe; Hosomi
Chemical Communications, 2001 , # 4 p. 357 - 358
反应条件
1: in diethyl ether
T=0°C; 1 h;
2: With water; ammonium chloride in diethyl ether
参考文献
DeGoey, David A.; Flentge, Charles A.; Flosi, William J.; Grampovnik, David J.; Kempf, Dale J.; Klein, Larry L.
Patent: US2005/131017 A1, 2005 ;
Location in patent: Page/Page column 150 ;
反应条件
in diethyl ether
T=-78 - 0°C; 1.5 h;
参考文献
Shen, Kao-Hsien; Yao, Ching-Fa
Journal of Organic Chemistry, 2006 , vol. 71, # 10 p. 3980 - 3983
反应条件
samarium diiodide in tetrahydrofuran
0.0833333 h; Ambient temperature;
参考文献
Souppe, J.; Namy, J. L.; Kagan, H. B.
Tetrahedron Letters, 1982 , vol. 23, # 34 p. 3497 - 3500
Title/Abstract Full Text View citing articles Show Details
Souppe, J.; Danon, L.; Namy, J.L.; Kagan, H.B.
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. 227 - 236
反应条件
1: lithium diisopropylamide / tetrahydrofuran / -78 °C
2: diisobutylaluminum hydride / CH2Cl2 / -78 °C
3: triethylamine / acetonitrile / 15 °C
4: trimethyl phosphite / 11 h / Heating
5: 65 percent / aq. sodium hydroxide / 2 h / Ambient temperature
View Scheme
参考文献
Kowalski, Conrad J.; Dung, Jen-Sen
Journal of the American Chemical Society, 1980 , vol. 102, # 27 p. 7950 - 7951
