1-苯基茚; 1-苯基-1H-茚合成路线 （共 29 条）
反应条件
1: 65 percent / FeCl3 / 12 h / 100 °C
2: 85 percent / CuI; P(t-Bu)3; diisopropylamine / Pd(PhCN)2Cl2 / toluene / 10 h / 20 °C
3: 92 percent / K2CO3; MeOH / CH2Cl2 / 2 h / 25 °C
4: 62 percent / TpRuPPh3(MeCN)2SbF6 / toluene / 36 h / 105 °C
View Scheme
参考文献
Odedra, Arjan; Datta, Swarup; Liu, Rai-Shung
Journal of Organic Chemistry, 2007 , vol. 72, # 9 p. 3289 - 3292
参考文献
ENICHEM S.p.A.
Patent: EP806436 A1, 1997 ;
反应条件
C22H30AuNP(1+) in dichloromethane
T=23°C; 24 h;
参考文献
McGonigal, Paul R.; De Leon, Claudia; Wang, Yahui; Homs, Anna; Solorio-Alvarado, Cesar R.; Echavarren, Antonio M.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 52 p. 13093 - 13096
反应条件
2-(dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl Au bis(trifluoromethylsulfonyl)imide in 1,2-dichloro-ethane
T=80°C; 10 h;
参考文献
Shu, Chao; Chen, Cheng-Bin; Chen, Wei-Xi; Ye, Long-Wu
Organic Letters, 2013 , vol. 15, # 21 p. 5542 - 5545
反应条件
1: sodium tetrahydroborate / dichloromethane / 20 °C
2: anhydrous iron chloride / 10 h / 100 °C
3: diisopropylamine; bis(benzonitrile)palladium(II) dichloride; copper(l) iodide / toluene / 10 h / 110 °C
4: potassium carbonate / methanol / 20 °C
5: bis-(trifluoromethylsulphonyl)amine; platinum (II) chloride / 1,2-dichloro-ethane / 10 h / 80 °C
View Scheme
参考文献
Shu, Chao; Chen, Cheng-Bin; Chen, Wei-Xi; Ye, Long-Wu
Organic Letters, 2013 , vol. 15, # 21 p. 5542 - 5545
反应条件
1: potassium carbonate / methanol / 20 °C
2: 2-(dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl Au bis(trifluoromethylsulfonyl)imide / 1,2-dichloro-ethane / 10 h / 80 °C
View Scheme
参考文献
Shu, Chao; Chen, Cheng-Bin; Chen, Wei-Xi; Ye, Long-Wu
Organic Letters, 2013 , vol. 15, # 21 p. 5542 - 5545
反应条件
1: sodium tetrahydroborate / dichloromethane / 20 °C
2: anhydrous iron chloride / 10 h / 100 °C
3: diisopropylamine; bis(benzonitrile)palladium(II) dichloride; copper(l) iodide / toluene / 10 h / 110 °C
4: potassium carbonate / methanol / 20 °C
5: 2-(dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl Au bis(trifluoromethylsulfonyl)imide / 1,2-dichloro-ethane / 10 h / 80 °C
View Scheme
参考文献
Shu, Chao; Chen, Cheng-Bin; Chen, Wei-Xi; Ye, Long-Wu
Organic Letters, 2013 , vol. 15, # 21 p. 5542 - 5545
反应条件
1: anhydrous iron chloride / 10 h / 100 °C
2: diisopropylamine; bis(benzonitrile)palladium(II) dichloride; copper(l) iodide / toluene / 10 h / 110 °C
3: potassium carbonate / methanol / 20 °C
4: 2-(dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl Au bis(trifluoromethylsulfonyl)imide / 1,2-dichloro-ethane / 10 h / 80 °C
View Scheme
参考文献
Shu, Chao; Chen, Cheng-Bin; Chen, Wei-Xi; Ye, Long-Wu
Organic Letters, 2013 , vol. 15, # 21 p. 5542 - 5545
反应条件
1: diisopropylamine; bis(benzonitrile)palladium(II) dichloride; copper(l) iodide / toluene / 10 h / 110 °C
2: potassium carbonate / methanol / 20 °C
3: 2-(dicyclohexylphosphino)-2',4',6'-triisopropylbiphenyl Au bis(trifluoromethylsulfonyl)imide / 1,2-dichloro-ethane / 10 h / 80 °C
View Scheme
参考文献
Shu, Chao; Chen, Cheng-Bin; Chen, Wei-Xi; Ye, Long-Wu
Organic Letters, 2013 , vol. 15, # 21 p. 5542 - 5545
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.67 h / -78 °C / |Inert atmosphere
1.2: 5 h / 20 °C / |Inert atmosphere
2.1: dichloro(2-pyridinecarboxylato)gold / dichloromethane / 1 h / 0 °C
View Scheme
参考文献
McGonigal, Paul R.; De Leon, Claudia; Wang, Yahui; Homs, Anna; Solorio-Alvarado, Cesar R.; Echavarren, Antonio M.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 52 p. 13093 - 13096
