1-苯基茚; 1-苯基-1H-茚合成路线 （共 29 条）
反应条件
1: N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide / water / 19 h / 20 °C / |Inert atmosphere
2: silver tetrafluoroborate / 1,2-dichloro-ethane / 2.5 h / 65 °C / |Inert atmosphere
3: triphenylphosphine; palladium dichloride; piperidine / water; acetone / 45 h / 20 °C / |Inert atmosphere
View Scheme
参考文献
Rosocha, Gregory; Batey, Robert A.
Tetrahedron, 2013 , vol. 69, # 41 p. 8758 - 8768
反应条件
in hexane; pentane
T=20°C; 2.5 h; Yield given. Yields of byproduct given;
参考文献
Tanaka, Jiro; Nojima, Masatomo; Kusabayashi, Shigekazu
Journal of the American Chemical Society, 1987 , vol. 109, # 11 p. 3391 - 3397
反应条件
(i) LiAlH4, Et2O, benzene, (ii) KHSO4; Multistep reaction;
参考文献
Duerr,H.
Chemische Berichte, 1970 , vol. 103, p. 369 - 379
参考文献
Berno, Piero; Ceccon, Alberto; Gambaro, Alessandro; Venzo, Alfonso
Tetrahedron Letters, 1988 , vol. 29, # 28 p. 3489 - 3492
反应条件
potassium tert-butylate
1) ether, liquid ammonia, 2) irradiation (BiCl3 filter), 30 min (90 min); Yield given. Multistep reaction. Further byproducts given;
参考文献
Tolbert, Laren M.; Siddiqui, Shahabuddin
Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1744 - 1751
反应条件
potassium tert-butylate
1) Me2SO, 2) irradiation (BiCl3 filter), 50 min; Yield given. Multistep reaction;
参考文献
Tolbert, Laren M.; Siddiqui, Shahabuddin
Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1744 - 1751
反应条件
potassium tert-butylate
1) ether, liquid ammonia, 2) irradiation (BiCl3 filter), 30 min (90 min); Yield given. Multistep reaction. Further byproducts given;
参考文献
Tolbert, Laren M.; Siddiqui, Shahabuddin
Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1744 - 1751
反应条件
potassium tert-butylate
1) Me2SO, 2) irradiation (BiCl3 filter), 50 min; Yield given. Multistep reaction;
参考文献
Tolbert, Laren M.; Siddiqui, Shahabuddin
Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1744 - 1751
反应条件
potassium tert-butylate
1) ether, liquid ammonia, 2) irradiation (BiCl3 filter), 30 min (90 min); Yield given. Multistep reaction. Further byproducts given;
参考文献
Tolbert, Laren M.; Siddiqui, Shahabuddin
Journal of Organic Chemistry, 1984 , vol. 49, # 10 p. 1744 - 1751
