2,3,4-三甲氧基苯酚合成路线 （共 32 条）
反应条件
in chloroform Oxidation; 3 h; Heating; Further byproducts given;
参考文献
Journal of Chemical Research, Miniprint, , # 8 p. 2001 - 2019
反应条件
T=0°C; Erhitzen des Reaktionsprodukts mit Wasser,Zink-Pulver und wenig AgNO3;
参考文献
Chemische Berichte, , vol. 73, p. 795,802
反应条件
1: With triethylamine; magnesium chloride in tetrahydrofuran 4 h; Inert atmosphereReflux; 2: With palladium 10 on activated carbon; hydrogen in ethanol P=25858.1 Torr; 4 h;
参考文献
Vera, William J.; Chinea, Kimberly; Banerjee, Ajoy K.
Journal of Chemical Research, 2009 , # 3 p. 186 - 187
反应条件
1: aq. ethanol 2: H2 / copper chromite / dioxane View Scheme
参考文献
Sato,K. et al.
Bulletin of the Chemical Society of Japan, 1972 , vol. 45, p. 3455 - 3457
反应条件
1: boric acid, acetic acid, methyl borate, H2 / 10percent Pd-C / 4 h / 190 °C / 45600 Torr 2: 95.7 percent / ferric chloride*6 H2O / benzene; H2O / 3 h / Ambient temperature View Scheme
参考文献
Sato,K. et al.
Bulletin of the Chemical Society of Japan, 1972 , vol. 45, p. 3455 - 3457
反应条件
1: 97 percent / K2CO3 / acetone / 22 h / Heating 2: 92 percent / Br2 / CH2Cl2 / -10 °C 3: 1.) n-BuLi / 1.) Et2O, 30 min, 2.) Et2O, 1 h, low temperature, 10 h, room temperature, 3 h, reflux View Scheme
参考文献
Syper, L.; Kloc, K.; Mlochowski, J.
Tetrahedron, 1980 , vol. 36, # 1 p. 123 - 129
反应条件
1.1: potassium carbonate / acetone / 0 - 20 °C / Inert atmosphere 2.1: trichlorophosphate / 0.33 h / 20 °C 2.2: 6 h / 60 °C 3.1: selenium(IV) oxide; dihydrogen peroxide / tert-butyl alcohol / 2.5 h / 50 °C 4.1: triethylamine / methanol / 0 - 20 °C 5.1: potassium carbonate / acetone / 36 h / 20 °C / Inert atmosphere 6.1: AlCl3, aluminium chloride / dichloromethane / 0 - 20 °C 7.1: lithium hexamethyldisilazane / tetrahydrofuran / -30 - 0 °C / Inert atmosphere 8.1: trifluoroacetic acid / methanol / 24 h / 50 °C View Scheme
参考文献
Chemical Communications, , vol. 47, # 10 p. 2868 - 2870
反应条件
1: K2CO3 / acetone; benzene 2: AlCl3 / CS2 / Heating 3: K2CO3 / acetone; dimethylformamide / Heating 4: AcOOH, HClO4, Ac2O 5: KOH / ethanol / Heating View Scheme
参考文献
Asakawa, Tomohiro; Hiza, Aiki; Nakayama, Miho; Inai, Makoto; Oyama, Dai; Koide, Hiroyuki; Shimizu, Kosuke; Wakimoto, Toshiyuki; Harada, Norihiro; Tsukada, Hideo; Oku, Naoto; Kan, Toshiyuki
Chemical Communications, 2011 , vol. 47, # 10 p. 2868 - 2870
反应条件
1: K2CO3 / acetone; benzene 2: AlCl3 / CS2 / Heating View Scheme
参考文献
Huee,R. et al.
Bulletin de la Societe Chimique de France, 1970 , p. 3617 - 3624
反应条件
oxygen; copper dichloride in water; ethyl acetate T=70°C; 3 h;
参考文献
Matsumoto, Masakatsu; Kobayashi, Hisako; Hotta, Yasushi
Synthetic Communications, 1985 , vol. 15, # 6 p. 515 - 520
