hydrogen; rhodium(I)-(S,S)-skewphos complexes in tetrahydrofuran Ambient temperature; Yield given;

hydrogen; triethylamine; Rh(I)-phosphine 22 in ethanol T=20°C; P=41371.8 Torr; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

in water T=80°C;

暂无反应条件数据

1: potassium carbonate / acetone 2: lithium borohydride / ethanol / 20 °C 3: Dess-Martin periodane 4: triphenylphosphine / dichloromethane 5: n-butyllithium / -78 °C 6: hydrogen 7: titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate / dichloromethane / -20 °C 8: methanesulfonyl chloride; triethylamine / 0 °C / Reflux 9: hydrogenchloride / tetrahydrofuran 10: sodium hydrogencarbonate 11: triethylamine / 0 °C 12: sodium hydride / N,N-dimethyl-formamide 13: hydrogenchloride / methanol View Scheme