sulfocalix[4]arene; hydrogen; triphenylphosphine; acetylacetonatodicarbonylrhodium in water; toluene
T=50°C; P=7500.6 Torr; 6 h; Title compound not separated from byproducts;
bis[(S,S,S)-DiazaPhos-SPE]; [rhodium(I)(carbonyl)2(acetylacetonate)]; hydrogen in tetrahydrofuran; toluene
T=40°C; P=8000.32 Torr; 4 h; optical yield given as percent eeenantioselective reaction;
参考文献
McDonald, Richard I.; Wong, Gene W.; Neupane, Ram P.; Stahl, Shannon S.; Landis, Clark R.
Journal of the American Chemical Society, 2010 , vol. 132, # 40 p. 14027 - 14029
pyridine; 2,2'-azo-bisisobutyronitrile; n-Bu3SnD
1.) PhH, reflux; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Kim, Sunggak; Yeon, Kyu Man; Yoon, Kwang Sub
Tetrahedron Letters, 1997 , vol. 38, # 22 p. 3919 - 3922
