2,2,5-三甲基-4-环庚烯-1-酮合成路线 （共 39 条）
反应条件
hydroxylamine hydrochloride; sodium acetate in methanol T=20°C;
参考文献
Justicia, Jose; Oltra, J. Enrique; Cuerva, Juan M.
Journal of Organic Chemistry, 2005 , vol. 70, # 21 p. 8265 - 8272
反应条件
Dess-Martin periodane in dichloromethane; water
T=20°C; 2 h;
参考文献
Justicia, Jose; Oltra, J. Enrique; Cuerva, Juan M.
Journal of Organic Chemistry, 2005 , vol. 70, # 21 p. 8265 - 8272
反应条件
K-10 Montmorillonite clay in benzene
T=30°C; Rearrangement; 6 h;
参考文献
Roy
Journal of Agricultural and Food Chemistry, 1999 , vol. 47, # 12 p. 5209 - 5210
反应条件
methylaluminium bis(trifluoroacetate) in hexane; dichloromethane
1.) 0 deg C, 10 min, 2.) 25 deg C, 3 h;
参考文献
Itoh, Akira; Oshima, Koichiro; Yamamoto, Hisashi; Nozaki, Hitosi
Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 7 p. 2050 - 2054
反应条件
Rhodium trichloride; sodium carbonate
T=200°C; 10 h;
参考文献
Uneyama, Kenji; Date, Takasi; Torii, Sigeru
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3160 - 3163
反应条件
1: NaBr / acetonitrile; H2O / 9 h / Ambient temperature; electrolysis
2: NaOH / acetonitrile; H2O / 1 h / Ambient temperature
3: 92 percent / H2(g), quinoline / 5percent Pd/BaSO4 / methanol / Ambient temperature
4: 1.) NaH / 1.) THF, RT, 1 h, 2.) THF, 20 min
5: tetrahydrofuran / 0.33 h
6: 200 °C
View Scheme
参考文献
Uneyama, Kenji; Date, Takasi; Torii, Sigeru
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3160 - 3163
反应条件
1: NaOH / acetonitrile; H2O / 1 h / Ambient temperature
2: 92 percent / H2(g), quinoline / 5percent Pd/BaSO4 / methanol / Ambient temperature
3: 1.) NaH / 1.) THF, RT, 1 h, 2.) THF, 20 min
4: tetrahydrofuran / 0.33 h
5: 200 °C
View Scheme
参考文献
Uneyama, Kenji; Date, Takasi; Torii, Sigeru
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3160 - 3163
反应条件
1: 92 percent / H2(g), quinoline / 5percent Pd/BaSO4 / methanol / Ambient temperature
2: 1.) NaH / 1.) THF, RT, 1 h, 2.) THF, 20 min
3: tetrahydrofuran / 0.33 h
4: 200 °C
View Scheme
参考文献
Uneyama, Kenji; Date, Takasi; Torii, Sigeru
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3160 - 3163
反应条件
1: 75 percent / NaBr / acetonitrile; tetrahydrofuran; H2O / 9 h / Ambient temperature; electroepoxidation
2: 20 percent / p-TsOH / CH2Cl2 / 0.5 h / Ambient temperature
3: 97 percent / H2(g), quinoline / 5percent Pd/BaSO4 / methanol / Ambient temperature
4: 44 percent / 0.5 h / 200 °C
View Scheme
参考文献
Uneyama, Kenji; Date, Takasi; Torii, Sigeru
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3160 - 3163
反应条件
1: 97 percent / H2(g), quinoline / 5percent Pd/BaSO4 / methanol / Ambient temperature
2: 44 percent / 0.5 h / 200 °C
View Scheme
参考文献
Uneyama, Kenji; Date, Takasi; Torii, Sigeru
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3160 - 3163
