2,2,5-三甲基-4-环庚烯-1-酮合成路线 （共 39 条）
反应条件
Dowex 50WX10 resin
T=200°C; 24 h; Further byproducts given;
参考文献
Ho, Tse-Lok; Liu, Shing-Hou
Liebigs Annalen der Chemie, 1983 , # 5 p. 761 - 769
参考文献
Uneyama, Kenji; Date, Takasi; Torii, Sigeru
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3160 - 3163
反应条件
1: CH2Cl2 / -78 °C
2: 85 percent / hydrogen peroxide / tetrahydrofuran / 1.) 0 -> 25 deg C, 2.) 25 deg C, 24 h
3: RhCl3 / Ambient temperature
View Scheme
参考文献
Konstantinovic, S.; Bugarcic, Z.; Marjanovic, Lj.; Gojkovic, S.; Mihailovic, M. Lj.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1998 , vol. 37, # 11 p. 1169 - 1170
反应条件
1: 89 percent / KOH / methanol / 5 h / Ambient temperature
2: 85 percent / 1 h / 200 °C
View Scheme
参考文献
Uneyama, Kenji; Date, Takasi; Torii, Sigeru
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3160 - 3163
反应条件
potassium hydrogensulfate
T=200°C; 0.5 h;
参考文献
Uneyama, Kenji; Date, Takasi; Torii, Sigeru
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3160 - 3163
反应条件
pyridinium p-toluenesulfonate in benzene
T=80°C; 1 h;
参考文献
Gurudutt, K. N.; Pasha, M. A.; Ravindranath, B.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 820 - 823
反应条件
zinc dibromide in benzene
T=80°C; 15 h;
参考文献
Gurudutt, K. N.; Pasha, M. A.; Ravindranath, B.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 820 - 823
反应条件
2: 70 percent / 3 h / 160 °C
3: 45 percent / HgCl2 / acetonitrile; H2O / 12 h / Heating
View Scheme
参考文献
Cairns, Peter M.; Crombie, Leslie; Pattenden, Gerald
Tetrahedron Letters, 1982 , vol. 23, # 13 p. 1405 - 1408
反应条件
3: 70 percent / 3 h / 160 °C
4: 45 percent / HgCl2 / acetonitrile; H2O / 12 h / Heating
View Scheme
参考文献
Cairns, Peter M.; Crombie, Leslie; Pattenden, Gerald
Tetrahedron Letters, 1982 , vol. 23, # 13 p. 1405 - 1408
反应条件
3: 70 percent / 3 h / 160 °C
4: 45 percent / HgCl2 / acetonitrile; H2O / 12 h / Heating
View Scheme
参考文献
Cairns, Peter M.; Crombie, Leslie; Pattenden, Gerald
Tetrahedron Letters, 1982 , vol. 23, # 13 p. 1405 - 1408
