1-乙基-1,4-环己二烯合成路线 （共 15 条）
反应条件
ammonia; sodium in ethanol
参考文献
Rodriguez, J.; Brun, P.; Waegell, B.
Journal of Organometallic Chemistry, 1989 , vol. 359, p. 343 - 370
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2 in benzene-d6 5 h; Ambient temperature; Further byproducts given;
参考文献
Gassman, Paul G.; Bonser, Steven M.; Mlinaric-Majerski, Kata
Journal of the American Chemical Society, 1989 , vol. 111, # 7 p. 2652 - 2662
反应条件
ammonia; sodium in methanol T=-75 - -33°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Beger, J.; Thomas, B.; Vogel, T.; Kirmse, K.; Lang, R.
Journal fuer Praktische Chemie (Leipzig), 1991 , vol. 333, # 3 p. 481 - 488
反应条件
ammonia; lithium; tert-butyl alcohol in tetrahydrofuran T=20°C; Birch reduction; Cooling with ice;
参考文献
Menzek, Abdullah; Karakaya, Melek Goekmen; Kaya, Afsin Ahmet
Helvetica Chimica Acta, 2008 , vol. 91, # 12 p. 2299 - 2307
反应条件
ammonia; lithium; tert-butyl alcohol in tetrahydrofuran T=20°C; Birch reduction; Cooling with ice;
参考文献
Menzek, Abdullah; Karakaya, Melek Goekmen; Kaya, Afsin Ahmet
Helvetica Chimica Acta, 2008 , vol. 91, # 12 p. 2299 - 2307
反应条件
[{Rh(μ-Cl)(1,5-cyclooctadiene)}2] in benzene-d6 Ambient temperature; Further byproducts given;
参考文献
Gassman, Paul G.; Mlinaric-Majerski, Kata
Tetrahedron Letters, 1988 , vol. 29, # 38 p. 4803 - 4806
反应条件
[RhCl(η2:η2-cycloocta-1,5-diene)]2 in benzene-d6 5 h; Ambient temperature<Rh(CO)2Cl>2 instead of <Rh(COD)Cl>2; Product distribution;
参考文献
Gassman, Paul G.; Bonser, Steven M.; Mlinaric-Majerski, Kata
Journal of the American Chemical Society, 1989 , vol. 111, # 7 p. 2652 - 2662
反应条件
potassium tert-butylate in dimethyl sulfoxide T=25°C; ΔG0, ΔH0, ΔS0 of isomerization; Thermodynamic data;
参考文献
Taskinen, Esko; Nummelin, Kari
Tetrahedron, 1994 , vol. 50, # 40 p. 11693 - 11698
反应条件
potassium tert-butylate in dimethyl sulfoxide T=25°C; ΔG0,ΔH0, ΔS0 of isomerization; Thermodynamic data;
参考文献
Taskinen, Esko; Nummelin, Kari
Tetrahedron, 1994 , vol. 50, # 40 p. 11693 - 11698
反应条件
potassium tert-butylate in dimethyl sulfoxide T=25°C; ΔG0, ΔH0, ΔS0 of isomerization; Thermodynamic data;
参考文献
Taskinen, Esko; Nummelin, Kari
Tetrahedron, 1994 , vol. 50, # 40 p. 11693 - 11698
