N-(叔丁氧羰基)-2-硝基苯酰胺合成路线 （共 16 条）
反应条件
4-(N,N-dimethlyamino)pyridine; triethylamine in dichloromethane T=20°C; Acylation; 0.416667 h;
参考文献
Fukuyama, Tohru; Cheung, Mui; Kan, Toshiyuki
Synlett, 1999 , # 8 p. 1301 - 1303
反应条件
1: (R)-phenylethylene oxide With water; (S,S)-[1,2-cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]cobaltIII*OAc in tetrahydrofuran T=0 - 20°C; 16 h; 2: N-Boc-2-nitrobenzenesulfonamide With oxygen in tetrahydrofuran T=20°C; 72 h; Title compound not separated from byproducts;
参考文献
Kim, Sang Kyun; Jacobsen, Eric N.
Angewandte Chemie - International Edition, 2004 , vol. 43, # 30 p. 3952 - 3954
参考文献
Kim, Sang Kyun; Jacobsen, Eric N.
Angewandte Chemie - International Edition, 2004 , vol. 43, # 30 p. 3952 - 3954
反应条件
1: 2-(3-chlorophenyl)oxirane With water; (S,S)-[1,2-cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]cobaltIII*OAc in tetrahydrofuran T=0 - 20°C; 16 h; 2: N-Boc-2-nitrobenzenesulfonamide With oxygen in tetrahydrofuran T=20°C; 72 h; Title compound not separated from byproducts;
参考文献
Kim, Sang Kyun; Jacobsen, Eric N.
Angewandte Chemie - International Edition, 2004 , vol. 43, # 30 p. 3952 - 3954
参考文献
Kim, Sang Kyun; Jacobsen, Eric N.
Angewandte Chemie - International Edition, 2004 , vol. 43, # 30 p. 3952 - 3954
反应条件
1: MEP With water; (S,S)-[1,2-cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]cobaltIII*OAc in tetrahydrofuran T=0 - 20°C; 24 h; 2: N-Boc-2-nitrobenzenesulfonamide in tetrahydrofuran T=20°C; 24 h;
参考文献
Kim, Sang Kyun; Jacobsen, Eric N.
Angewandte Chemie - International Edition, 2004 , vol. 43, # 30 p. 3952 - 3954
反应条件
1: epichlorohydrin With water; (S,S)-[1,2-cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]cobaltIII*OAc in tetrahydrofuran T=0 - 20°C; 24 h; 2: N-Boc-2-nitrobenzenesulfonamide in tetrahydrofuran T=20°C; 24 h;
参考文献
Kim, Sang Kyun; Jacobsen, Eric N.
Angewandte Chemie - International Edition, 2004 , vol. 43, # 30 p. 3952 - 3954
反应条件
1: PPh3; DEAD / tetrahydrofuran 2: TFA / CH2Cl2 / 4 h View Scheme
参考文献
Ovaa, Huib; Stapper, Christian; Van Der Marel, Gijs A; Overkleeft, Hermen S; Van Boom, Jacques H; Blechert, Siegfried
Tetrahedron, 2002 , vol. 58, # 37 p. 7503 - 7518
反应条件
1: 4-chlorostyrene oxide With water; (S,S)-[1,2-cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]cobaltIII*OAc in tetrahydrofuran T=0 - 20°C; 16 h; 2: N-Boc-2-nitrobenzenesulfonamide With oxygen in tetrahydrofuran T=20°C; 72 h; Title compound not separated from byproducts;
参考文献
Kim, Sang Kyun; Jacobsen, Eric N.
Angewandte Chemie - International Edition, 2004 , vol. 43, # 30 p. 3952 - 3954
参考文献
Kim, Sang Kyun; Jacobsen, Eric N.
Angewandte Chemie - International Edition, 2004 , vol. 43, # 30 p. 3952 - 3954
