hydrogen; platinum(IV) oxide in ethanol

disodium hydrogenphosphate; sodium dihydrogenphosphate; Fremy’s salt

暂无反应条件数据

1: 1) LiPdCl4, NaOAc, 2) NEt3 / 1a) MeOH, 0 deg C, 10 min, 1b) r.t., 24 h, 2a) glac. acetic acid, CHCl3, 0 deg C, 10 min, 2b) r.t., 24-48 h 2: hexane; benzene / 2 h / Ambient temperature 3: NEt3 / tetrahydrofuran / 2 h / Ambient temperature 4: Li, NH3 / tetrahydrofuran / 0.25 h / -78 °C 5: 80 percent / Fremy's salt, Na2HPO4, NaH2PO4 / Adogen / CH2Cl2; H2O / Ambient temperature View Scheme