1-硫代-b-D-葡萄糖四乙酸酯合成路线 （共 55 条）
反应条件
potassium carbonate in water; acetone 0.3 h; Ambient temperature;
参考文献
Driguez; Szeja
Synthesis, 1994 , # 12 p. 1413 - 1414
反应条件
potassium carbonate; acetone
参考文献
Cerny; Pacak
Collection of Czechoslovak Chemical Communications, 1959 , vol. 24, p. 2566,2567
反应条件
1: 2,3,4,6-Tetra-O-acetyl-1-thio-β-D-glucopyranose; tri-O-acetyl-D-allal With 1,2-diphenyl-1-keto-2,2-dimethoxyethane in ethanol; dichloromethane T=20°C; 1 h; UV-irradiation; 2: acetic anhydride With pyridine T=20°C; 2 h; optical yield given as percent deregioselective reaction;
参考文献
Staderini, Samuele; Chambery, Angela; Marra, Alberto; Dondoni, Alessandro
Tetrahedron Letters, 2012 , vol. 53, # 6 p. 702 - 704
反应条件
1: 2,3,4,6-Tetra-O-acetyl-1-thio-β-D-glucopyranose; tri-O-acetyl-D-galactal With 1,2-diphenyl-1-keto-2,2-dimethoxyethane in ethanol; dichloromethane T=20°C; 1 h; UV-irradiation; 2: acetic anhydride With pyridine T=20°C; 2 h; optical yield given as percent deregioselective reaction;
参考文献
Staderini, Samuele; Chambery, Angela; Marra, Alberto; Dondoni, Alessandro
Tetrahedron Letters, 2012 , vol. 53, # 6 p. 702 - 704
反应条件
1: 2,3,4,6-Tetra-O-acetyl-1-thio-β-D-glucopyranose With sodium hydride in tetrahydrofuran T=20°C; 1 h; Inert atmosphere; 2: With 18-crown-6 ether in tetrahydrofuran T=-18 - 20°C; 24 h; 3: acetic anhydride Further stages;
参考文献
Repetto, Evangelina; Manzano, Veronica E.; Uhrig, Maria Laura; Varela, Oscar
Journal of Organic Chemistry, 2012 , vol. 77, # 1 p. 253 - 265
参考文献
Cerny et al.
Collection of Czechoslovak Chemical Communications, 1959 , vol. 24, p. 64,67
反应条件
1: 2,3,4,6-Tetra-O-acetyl-1-thio-β-D-glucopyranose With methanol; sodium methylate T=20°C; Zemplen deacetylation; 2: Ph2SO2SPh in methanol T=0 - 20°C;
参考文献
Montel, Emilie; Hrmova, Maria; Fincher, Geoffrey B.; Driguez, Hugues; Cottaz, Sylvain
Australian Journal of Chemistry, 2009 , vol. 62, # 6 p. 575 - 584
反应条件
diethylazodicarboxylate in tetrahydrofuran
T=20°C; 3 h;
参考文献
Ribeiro Morais, Goreti; Falconer, Robert A.
Tetrahedron Letters, 2007 , vol. 48, # 43 p. 7637 - 7641
反应条件
1.1: silver(I) acetate / ethyl acetate / 0.67 h / 20 °C
1.2: 0.17 h / 0 - 20 °C
2.1: dichloromethane / 0.75 h / 20 °C
View Scheme
参考文献
Illyes, Tuende-Zita; Szabo, Tamas; Szilagyi, Laszlo
Carbohydrate Research, 2011 , vol. 346, # 12 p. 1622 - 1627
反应条件
diethylazodicarboxylate in tetrahydrofuran
T=20°C; 3 h;
参考文献
Ribeiro Morais, Goreti; Falconer, Robert A.
Tetrahedron Letters, 2007 , vol. 48, # 43 p. 7637 - 7641
